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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Taccardi, Nicola |
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Ali, M. A. |
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Azevedo, Nuno Monteiro |
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article
A coprecipitation technique to prepare BaNb2O6
Abstract
<p>A mixture of ammonium oxalate and ammonium hydroxide was used to coprecipitate barium and niobium ions as barium oxalate and niobium hydroxide under basic conditions. This precursor on calcination at 750°C yielded BaNb<sub>2</sub>O<sub>6</sub> ceramics. This is a much lower temperature as compared to that prepared by traditional solid-state method (1000°C), as reported for the formation of BaNb<sub>2</sub>O<sub>6</sub>. Transmission electron microscope (TEM) investigations revealed that the average particle size is 100 nm for the calcined powders. The room temperature dielectric constant at 1 kHz is found to be 1100. The ferroelectric hysteresis loop parameters of these samples were also studied.</p>