| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Kumar, Abhinav
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Optimization of surface roughness in milling of EN 24 steel with WC-Coated inserts using response surface methodology: analysis using surface integrity microstructural characterizationscitations
- 2024Biosurfactants in biocorrosion and corrosion mitigation of metals: An overviewcitations
- 2023The Microstructure and Properties of Ni-Si-La2O3 Coatings Deposited on 304 Stainless Steel by Microwave Claddingcitations
- 2023Prediction and simulation of mechanical properties of borophene-reinforced epoxy nanocomposites using molecular dynamics and FEAcitations
- 2023Effect of Pulsation in Microstructure and Mechanical Properties of Titanium Alloy-Annealed Welded Joints at Different Temperaturescitations
- 2022Diaminopyridine Hg(II)-based 1D supramolecular polymercitations
- 2022Ferrocene Appended Asymmetric Sensitizers with Azine Spacers with phenolic/nitro anchors for Dye-Sensitized Solar Cellscitations
- 2020A new 1D coordination polymer of triphenyl lead hydrosulfide: Synthesis and insights into crystal architecture and Hirshfeld surface analysescitations
- 2016Transition metal ferrocenyl dithiocarbamates functionalized dye-sensitized solar cells with hydroxy as an anchoring groupcitations
Places of action
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article
A new 1D coordination polymer of triphenyl lead hydrosulfide: Synthesis and insights into crystal architecture and Hirshfeld surface analyses
Abstract
A new Pb(IV)-based coordination polymer having formula [(C<SUB>6</SUB>H<SUB>5</SUB>)<SUB>3</SUB>Pb-SH]<SUB>n</SUB> (1) has been synthesized and characterized using microanalyses, multinuclear NMR and single crystal X-ray diffraction. The X-ray crystal structure reveals a distorted square pyramidal geometry (τ<SUB>5</SUB> = 0.19) around the central Pb(IV) center. The aromatic π-electron cloud is solely drifted to the anti-bonding σ*-orbital of Pb-S bond thereby forming intramolecular Pb⋯C tetrel bonding interaction; intramolecular S⋯H interaction also occurs in the linear chain of 1. The observed interactions have been discussed in detail and have been addressed critically by Hirshfeld surface analysis and fingerprint plots....