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Alarifi, Abdullah
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article
A new 1D coordination polymer of triphenyl lead hydrosulfide: Synthesis and insights into crystal architecture and Hirshfeld surface analyses
Abstract
A new Pb(IV)-based coordination polymer having formula [(C<SUB>6</SUB>H<SUB>5</SUB>)<SUB>3</SUB>Pb-SH]<SUB>n</SUB> (1) has been synthesized and characterized using microanalyses, multinuclear NMR and single crystal X-ray diffraction. The X-ray crystal structure reveals a distorted square pyramidal geometry (τ<SUB>5</SUB> = 0.19) around the central Pb(IV) center. The aromatic π-electron cloud is solely drifted to the anti-bonding σ*-orbital of Pb-S bond thereby forming intramolecular Pb⋯C tetrel bonding interaction; intramolecular S⋯H interaction also occurs in the linear chain of 1. The observed interactions have been discussed in detail and have been addressed critically by Hirshfeld surface analysis and fingerprint plots....