| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Chmurzyński, Lech
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2019MALDI-MS for polymer characterization: recent developments and future prospectscitations
- 2019A review of new approaches to analytical methods to determine the structure and morphology of polymerscitations
- 2018Kinetics and thermodynamic of reaction of oxydiacetate copper(II) complex with 2,2′-bipyridine and 1,10-phenanthroline in anionic and cationic surfactant solutionscitations
- 2017Structures, physicochemical and cytoprotective properties of new oxidovanadium(IV) complexes -[VO(mIDA)(dmbipy)]·1.5H2O and [VO(IDA)(dmbipy)]·2H2Ocitations
- 2017Kinetics and thermodynamics of the reaction of iminodiacetate copper(II) complexes with 1,10- phenanthroline and 2,2‘-bipyridine in aqueous, anionic, cationic and nonionic surfactants solutionscitations
- 2017Simultaneous determination of thermodynamic and kinetic parameters of aminopolycarbonate complexes of cobalt(II) and nickel(II) based on isothermal titration calorimetry datacitations
- 2016Influence of primary ligands (ODA, TDA) on physicochemical and biological properties of oxidovanadium (IV) complexes with bipy and phen as auxiliary ligandscitations
- 2015Physicochemical properties of ternary oxovanadium(IV) complexes with oxydiacetate and 1,10-phenanthroline or 2,2'-bipyridine: cytoprotective activity in hippocampal neuronal HT22 cellscitations
- 2012Thermal properties of potassium bis(oxalato)diaquochromates(III) in solid state. Trans-cis isomerization of the [Cr2O4)2(OH2)2</SUB>]- complex ion in aqueous solutionscitations
- 2011Investigation of copper(II) complexation by glycylglycine using isothermal titration calorimetrycitations
- 2008Determination of dissociation constants for coordination compounds of Cr(III) and Co(III) using potentiometric and spectrophotometric methodscitations
Places of action
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article
Structures, physicochemical and cytoprotective properties of new oxidovanadium(IV) complexes -[VO(mIDA)(dmbipy)]·1.5H2O and [VO(IDA)(dmbipy)]·2H2O
Abstract
New oxidovanadium(IV) complexes with a modification of the ligand in the VO2+ coordination sphere were synthesized. [VO(mIDA)(dmbipy)]∙1.5H2O and [VO(IDA)(dmbipy)]∙2H2O were obtained as dark green crystals and grey-green powder, respectively (mIDA = N-methyliminodiacetic anion, IDA = iminodiacetic anion, dmbipy = 4,4′-dimethoxy-2,2′-dipyridyl). The crystal structure of [VO(mIDA)(dmbipy)]·1.5H2O has been determined by the X-ray diffraction method. The studies of structure of [VO(mIDA)(dmbipy)]∙1.5H2O have shown that this compound occurs in the crystal as two rotational conformers. Furthermore, the stability constants of [VO(mIDA)(dmbipy)]∙1.5H2O and [VO(IDA)(dmbipy)]∙2H2O complexes in aqueous solutions were studied by using the potentiometric titration method and, consequently, determined using the Hyperquad2008 program. Moreover, the title complexes were investigated as antioxidant substances. The impact of the structure modification in the VO2+ complexes on the radical scavenging activity has been studied. The ability to scavenge the superoxide radical by two complexes - [VO(mIDA)(dmbipy)]·1.5H2O and [VO(IDA)(dmbipy)]·2H2O was studied by cyclic voltammetry (CV) and nitrobluetetrazolium (NBT) methods. The title complexes were also examined by the spectrophotometric method as scavengers of neutral organic radical - 1,1-diphenyl-2-picrylhydrazyl (DPPH∙) and radical cation - 2,2'-azinobis-(3-ethylbenzothiazoline)-6-sulfonic acid (ABTS∙+). Furthermore, the biological properties of two oxidovanadium(IV) complexes were investigated in relation to its cytoprotective properties by the MTT and LDH tests based on the hippocampal HT22 neuronal cell line during the oxidative damage induced by hydrogen peroxide. Finally, the results presented in this paper have shown that the both new oxidovanadium(IV) complexes with the 4,4′-dimethoxy-2,2′-dipyridyl ligand can be treated as the cytoprotective substances.