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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Scholz, Ricardo
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2014Vibrational spectroscopy of the sulphate mineral sturmanite from Kuruman manganese deposits, South Africacitations
- 2014Infrared and raman spectroscopic characterization of the borate mineral vonsenite Fe2/2+ Fe3+BO5citations
- 2014A vibrational spectroscopic study of the phosphate mineral churchite (REE)(PO4).2H2Ocitations
- 2013Vibrational spectroscopic characterization of the phosphate mineral kulanite Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3citations
- 2013Vibrational spectroscopic characterization of the phosphate mineral series eosphorite-childrenite-(Mn,Fe)Al(PO4)(OH)2.(H2O)citations
- 2013The phosphate mineral arrojadite-(KFe) and its spectroscopic characterizationcitations
- 2013Vibrational spectroscopic characterization of the phosphate mineral phosphophyllite - Zn2Fe(PO4)2.4H2O, from Hagendorf Sud, Germany and in comparison with other zinc phosphatescitations
- 2012Raman and infrared spectroscopic characterization of beryllonite, a sodium and beryllium phosphate mineral - implications for mineral collectorscitations
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article
Vibrational spectroscopic characterization of the phosphate mineral phosphophyllite - Zn2Fe(PO4)2.4H2O, from Hagendorf Sud, Germany and in comparison with other zinc phosphates
Abstract
This research was undertaken on phosphophyllite sample from the Hagendorf Süd pegmatite, Bavaria, Germany. Chemical analysis was carried out by Scanning Electron Microscope in the EDS mode and indicates a zinc and iron phosphate with partial substitution of manganese, which partially replaced iron. The calculated chemical formula of the studied sample was determined to be: Zn2(Fe0.65, Mn0.35)P1.00(PO4)2-�4(H2O). The intense Raman peak at 995 cm�1 is assigned to the m1 PO3� 4 symmetric stretching mode and the two Raman bands at 1073 and 1135 cm�1 to the m3 PO3� 4 antisymmetric stretching modes. The m4 PO3� 4 bending modes are observed at 505, 571, 592 and 653 cm�1 and the m2 PO3� 4 bending mode at 415 cm�1. The sharp Raman band at 3567 cm�1 attributed to the stretching vibration of OH units bringsinto question the actual formula of phosphophyllite. Vibrational spectroscopy enables an assessment ofthe molecular structure of phosphophyllite to be assessed.