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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Warżajtis, Beata
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2020Zinc(II) complexes with aromatic nitrogen-containing heterocycles as antifungal agents: Synergistic activity with clinically used drug nystatincitations
- 2020Modulation of the structure of octahedral 1,3-pdta-nickel(II) complex by introducing methyl substituents at the central 1,3-propanediamine carbon atom: Stereospecific formation and the crystal structure of [Mg(H2O)5Ni(2,2-diMe-1,3-pdta)]·1.5H2Ocitations
- 2017Mononuclear gold(iii) complexes with l-histidine-containing dipeptides: tuning the structural and biological properties by variation of the N-terminal amino acid and counter anioncitations
- 2017Mononuclear gold(III) complexes with phenanthroline ligands as efficient inhibitors of angiogenesis: A comparative study with auranofin and sunitinibcitations
- 2015Chalcogenated (S)-(-)-nicotine derivatives as chiral linkers for 1D coordination polymerscitations
- 2011Structural diversification of the coordination mode of divalent metals with 1,3-propanediaminetetraacetate (1,3-pdta): The missing crystal structure of the s-block metal complex [Sr<inf>2</inf>(1,3-pdta)(H<inf>2</inf>O) <inf>6</inf>]·H<inf>2</inf>Ocitations
- 2009Variety of polymorphic forms contrasted with uniform crystal packing in sparteine ML<inf>2</inf> complexes: Crystal structure, spectroscopic and magnetic properties of (-)-α-isosparteine and (-)-sparteine complexes with CuBr<inf>2</inf>citations
- 2008Coordination behaviour and two-dimensional-network formation in poly[[μ-aqua-diaqua-(μ5-propane-1,3-diyldinitrilo-tetra-acetato) -dilithium(I)-cobalt(II)] dihydrate]: The first example of an M <sup>II</sup>-1,3-pdta complex with a monovalent metal counter-ioncitations
- 2005Highly selective crystallization of metal(II) ions with 1,3-pdta ligand: Syntheses and crystal structures of the [Mg(H<inf>2</inf>O)<inf>6</inf>][Cd(1,3- pdta)(H<inf>2</inf>O)]·2H<inf>2</inf>O and two isomorphic [Zn(1,3-pdta)]<sup>2-</sup> complexescitations
- 2005Layered crystal structure of the trans(O<inf>5</inf>O<inf>6</inf>) isomer of potassium (1,3-propanediamine-N,N′-diacetato-N,N′-di-3- propionato)cobaltate(III) trihydrate, trans(O<inf>5</inf>O<inf>6</inf>)-K[Co(1, 3-pddadp)]·3H<inf>2</inf>O, stabilized by ionic, hydrogen bond and C=O dipolar interactionscitations
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article
Variety of polymorphic forms contrasted with uniform crystal packing in sparteine ML<inf>2</inf> complexes: Crystal structure, spectroscopic and magnetic properties of (-)-α-isosparteine and (-)-sparteine complexes with CuBr<inf>2</inf>
Abstract
<p>This paper reports the synthesis, thermogravimetric and magnetic measurements for (-)-α-isosparteine CuBr<sub>2</sub> complex (1) and the existence of the fourth polymorph (2) of (-)-sparteine CuBr<sub>2</sub> complex. The two CuBr<sub>2</sub> complexes have been structurally characterized by X-ray crystallography. A diverse supramolecular aggregation of (-)-sparteine CuBr<sub>2</sub> complex has been contrasted with strong tendency for isostructuralism observed in a series of ML<sub>2</sub> complexes (M = metal, L = halogen or pseudohalogen) with both sparteine (3) and α-isosparteine (4). The incidence of polymorphism in a group of compounds which readily form the isomorphic series is quite unusual. Moreover, the reported crystal structure of 2 constitutes the first example showing that the organization of metal complexes of sparteine isomers into similar packing architecture is possible, although in general configurational changes within the sparteine ligand differentiate packing of otherwise similar (-)-sparteine-ML<sub>2</sub> or (-)-α-isosparteine-ML<sub>2</sub> molecules. © 2009 Elsevier B.V. All rights reserved.</p>