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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Obot, Ime B.
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Topics
Publications (10/10 displayed)
- 2022Corrosion Inhibition of Rumex vesicarius Mediated Chitosan-AgNPs Composite for C1018 CS in CO2-Saturated 3.5% NaCl Medium under Static and Hydrodynamic Conditionscitations
- 2022Elucidation of corrosion inhibition property of compounds isolated from Butanolic Date Palm Leaves extract for low carbon steel in 15% HCl solutioncitations
- 2021Date palm leaves extract as a green and sustainable corrosion inhibitor for low carbon steel in 15 wt.% HCl solutioncitations
- 2021Effect of intensifier additives on the performance of butanolic extract of date palm leaves against the corrosion of api 5l x60 carbon steel in 15 wt.% hcl solutioncitations
- 2020Preparation of silver/chitosan nanofluids using selected plant extractscitations
- 2020Exploration of natural polymers for use as green corrosion inhibitors for AZ31 magnesium alloy in saline environmentcitations
- 2020Corrosion inhibition effect of a benzimidazole derivative on heat exchanger tubing materials during acid cleaning of multistage flash desalination plantscitations
- 2019Studies of the anticorrosion property of a newly synthesized Green isoxazolidine for API 5L X60 steel in acid environmentcitations
- 2018Comparative studies on the corrosion inhibition efficacy of ethanolic extracts of date palm leaves and seeds on carbon steel corrosion in 15% HCl solutioncitations
- 2018Exploration of Dextran for Application as Corrosion Inhibitor for Steel in Strong Acid Environmentcitations
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article
Elucidation of corrosion inhibition property of compounds isolated from Butanolic Date Palm Leaves extract for low carbon steel in 15% HCl solution
Abstract
<p>The present work reports on the corrosion inhibition property of compounds isolated from butanolic extract of Date Palm leaves for low carbon steel in 15% HCl solution. Six compounds were isolated from Date Palm leaves and purified using a combination of column chromatography, thin layer chromatography, and Prep HPLC-MS system. The isolated compounds were characterized using <sup>1</sup>H NMR, <sup>13</sup>C NMR, and GC–MS. Their identity was revealed to be a mixture of fatty alkanes, oleanolic acid (OA), vanillyl alcohol (VA), β-Sitosterol-3-O-β-D-glucoside (β-SSG), sucrose sugar, and carotenoid lutein. As a result of the amount of the different isolates obtained, only three out of the six compounds namely β-SSG, OA, and VA were tested for anticorrosion property for low carbon steel in 15% HCl. The corrosion inhibition of the isolated compounds was performed using weight loss and electrochemical techniques. Surface morphology analysis of the corroded steel in the absence and presence of the isolated compounds was undertaken using SEM/EDAX and 3D optical profilometer. Also, DFT calculations was performed in order to indicate the reactivities and bonding sites of the isolated molecules as well as Monte Carlos simulations (MCS) to determine the energy of interaction between the inhibitors and carbon steel surface. Results obtained show that the values of inhibition efficiency (IE) for the different isolated compounds at the concentration (35 ppm) studied follow the trend: β-SSG (46.57%) > VA<sub>isolated</sub> (39.30%) > VA<sub>commercial</sub> (36.81%) > OA (31.94%) at 25 °C. It is also noted that, for the isolated OA, IE increased with increase in concentration but decreased with increase in temperature. For isolated VA, IE decreased with increase in temperature. However, for the commercial VA, IE slightly increased with rise in temperature. The experimental results are in agreement with the theoretical prediction. In both predicted and experimental results, β-SSG is the best corrosion inhibitor.</p>