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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Willför, Stefan
Åbo Akademi University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2022Injectable thiol-ene hydrogel of galactoglucomannan and cellulose nanocrystals in delivery of therapeutic inorganic ions with embedded bioactive glass nanoparticlescitations
- 2022Injectable thiol-ene hydrogel of galactoglucomannan and cellulose nanocrystals in delivery of therapeutic inorganic ions with embedded bioactive glass nanoparticlescitations
- 2022The Hydrophobicity of Lignocellulosic Fiber Network Can Be Enhanced with Suberin Fatty Acids
- 2022Digital light processing (DLP) 3D-fabricated antimicrobial hydrogel with a sustainable resin of methacrylated woody polysaccharides and hybrid silver-lignin nanospherescitations
- 2021On Laccase-Catalyzed Polymerization of Biorefinery Lignin Fractions and Alignment of Lignin Nanoparticles on the Nanocellulose SurfaceviaOne-Pot Water-Phase Synthesiscitations
- 2021Bio-Based Hydrogels With Ion Exchange Properties Applied to Remove Cu(II), Cr(VI), and As(V) Ions From Watercitations
- 2021Removal of nafcillin sodium monohydrate from aqueous solution by hydrogels containing nanocellulosecitations
- 2021On Laccase-Catalyzed Polymerization of Biorefinery Lignin Fractions and Alignment of Lignin Nanoparticles on the Nanocellulose Surface via One-Pot Water-Phase Synthesiscitations
- 2021Removal of nafcillin sodium monohydrate from aqueous solution by hydrogels containing nanocellulose:An experimental and theoretical studycitations
- 2020Tailored thermosetting wood adhesive based on well-defined hardwood lignin fractionscitations
- 2020The Hydrophobicity of Lignocellulosic Fiber Network Can Be Enhanced with Suberin Fatty Acidscitations
- 2020Larch wood residues valorization through extraction and utilization of high value-added productscitations
- 2019The Hydrophobicity of Lignocellulosic Fiber Network Can Be Enhanced with Suberin Fatty Acidscitations
- 2018Novel biorenewable composite of wood polysaccharide and polylactic acid for three dimensional printingcitations
- 2017Mild oxalic-acid-catalyzed hydrolysis as a novel approach to prepare cellulose nanocrystalscitations
- 2016Softwood-based sponge gelscitations
- 2016Development of nanocellulose scaffolds with tunable structures to support 3D cell culturecitations
- 2015Tailor-made hemicellulose-based hydrogels reinforced with nanofibrillated cellulosecitations
- 2015Composite films of nanofibrillated cellulose and O-acetyl galactoglucomannan (GGM) coated with succinic esters of GGM showing potential as barrier material in food packagingcitations
- 2014Impact of torrefaction on the chemical structure of birch woodcitations
- 2011Oxidation of lignans and lignin model compounds by laccase in aqueous solvent systemscitations
- 2010Comparison of microencapsulation properties of spruce galactoglucomannans and arabic gum using a model hydrophobic core compoundcitations
- 2008Films from spruce galactoglucomannan blended with poly(vinyl alcohol), corn arabinoxylan, and konjac glucomannan
- 2008Kinetics of acid hydrolysis of water-soluble spruce O-acetyl galactoglucomannanscitations
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article
Removal of nafcillin sodium monohydrate from aqueous solution by hydrogels containing nanocellulose
Abstract
<p>In the present work, new biocomposite hydrogels were prepared based on the vinyl monomer 2-methacroyloxyethyltrimethyl ammonium chloride (ClAETA) in the presence of nanofibrillated cellulose (CNF) for the removal of the emerging contaminant nafcillin sodium monohydrate (NFX). The hydrogels were synthesized via free radicals, with the amount of CNF varied, and characterized by fourier transform infrared spectroscopy (FT-IR), thermal gravimetric analysis (TGA), and scanning electron microscope (SEM) techniques. The capacity to absorb water and to remove NFX was determined through batch studies. It was observed that the presence of CNF significantly promotes both properties, with a hydration capacity of 2100% and an NFX adsorption capacity of 45 mg g<sup>−1</sup> in P(ClAETA)1-12-2%CNF (pH 6, 0.01 g of adsorbent, initial concentration of NFX 200 mg g<sup>−1</sup>). The conformational study showed that in the most stable conformation, CNF avoids direct interaction with the NFX molecule. Herein, the main interactions are predominantly dominated by weak interactions such as London dispersion and electrostatic interactions between charged groups. Molecular dynamics simulations distinguish the existence of π-π stacking interactions between aromatic rings from NFX in the polymer + NFX system. Contact interactions were qualitatively and quantitatively characterized by the NCI index and the IGM analysis.</p>