| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Winter, M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Insights into the Impact of Activators on the ‘Catalytic’ Graphitization to Design Anode Materials for Lithium Ion Batteriescitations
- 2023Advanced Dual-Ion Batteries with High-Capacity Negative Electrodes Incorporating Black Phosphorus
- 2021Waste to life: Low-cost, self-standing, 2D carbon fiber green Li-ion battery anode made from end-of-life cotton textilecitations
- 2021X-ray molecular structure characterization of a hexamethylenetetramine zinc(II) porphyrin complex, catalytic degradation of toluidine blue dye, experimental and statistical studies of adsorption isothermscitations
- 2020A bilayer polymer electrolyte encompassing pyrrolidinium-based RTIL for binder-free silicon few-layer graphene nanocomposite anodes for Li-ion batterycitations
- 2020Assessment on the Use of High Capacity “Sn$_{4}$P$_{3}$”/NHC Composite Electrodes for Sodium-Ion Batteries with Ether and Carbonate Electrolytes
- 2017Investigation of nano-sized Cu(II)O as a high capacity conversion material for Li-metal cells and lithium-ion full cellscitations
- 2017Coexistence of conversion and intercalation mechanisms in lithium ion batteries: Consequences for microstructure and interaction between the active material and electrolytecitations
- 2016Nanoporous polymer foams derived from high molecular PS-b-P4VP(PDP)(x) for template-directed synthesis approachescitations
- 2013A Liquid Inorganic Electrolyte Showing an Unusually High Lithium Ion Transference Number: A Concentrated Solution of LiAlCl4 in Sulfur Dioxide
- 2011Malonate complexes of dysprosium: synthesis, characterization and application for LI-MOCVD of dysprosium containing thin filmscitations
- 2006Liquid injection MOCVD of ZrO2 thin films using a novel zirconium Bis(diethylamido)-bis(di-tert-butylmalonato) as a novel precursorcitations
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article
X-ray molecular structure characterization of a hexamethylenetetramine zinc(II) porphyrin complex, catalytic degradation of toluidine blue dye, experimental and statistical studies of adsorption isotherms
Abstract
In this work, we report the single crystal X-ray molecular structure of the pentacoordinate zinc(II) porphyrin coordination compound [Zn(TFMPP)(HMTA)] (complex (I)), where TFMPP = meso-tetrakis[(para-tetratrifluoromethylphenyl]porphyrinato and HMTA = hexamethylenetetramine. The 3D Hirshfeld surfaces and the 2D fingerprint maps have been employed to investigate the intermolecular interactions in the crystal lattice of complex (I). The main part of this paper is devoted to the use of the free base porphyrin H2TFMPP and the metalled zinc(II)-HMTA-porphyrin derivative (I) as adsorbents for the toluidine blue (BT) dye. The kinetic of the adsorption process for both H2TFMPP and complex (I) fitted well with the Pseudo-Second-Order kinetic model and the adsorption isotherms were well described by the Langmuir model. The advanced statistical physics models were used to provide good interpretations of the adsorption of the BT dye. Furthermore, complex (I) was found to be a good catalyst for the removal of this cationic dye in 30% aqueous hydrogen peroxide solution.<br/><br/>The theoretical thermodynamic analyses performed on the free base porphyrin H2TFMPP and complex (I) show that the adsorption of the BT pollutant on these porphyrin compounds is not only possible but also spontaneous.