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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Chmurzyński, Lech
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2019MALDI-MS for polymer characterization: recent developments and future prospectscitations
- 2019A review of new approaches to analytical methods to determine the structure and morphology of polymerscitations
- 2018Kinetics and thermodynamic of reaction of oxydiacetate copper(II) complex with 2,2′-bipyridine and 1,10-phenanthroline in anionic and cationic surfactant solutionscitations
- 2017Structures, physicochemical and cytoprotective properties of new oxidovanadium(IV) complexes -[VO(mIDA)(dmbipy)]·1.5H2O and [VO(IDA)(dmbipy)]·2H2Ocitations
- 2017Kinetics and thermodynamics of the reaction of iminodiacetate copper(II) complexes with 1,10- phenanthroline and 2,2‘-bipyridine in aqueous, anionic, cationic and nonionic surfactants solutionscitations
- 2017Simultaneous determination of thermodynamic and kinetic parameters of aminopolycarbonate complexes of cobalt(II) and nickel(II) based on isothermal titration calorimetry datacitations
- 2016Influence of primary ligands (ODA, TDA) on physicochemical and biological properties of oxidovanadium (IV) complexes with bipy and phen as auxiliary ligandscitations
- 2015Physicochemical properties of ternary oxovanadium(IV) complexes with oxydiacetate and 1,10-phenanthroline or 2,2'-bipyridine: cytoprotective activity in hippocampal neuronal HT22 cellscitations
- 2012Thermal properties of potassium bis(oxalato)diaquochromates(III) in solid state. Trans-cis isomerization of the [Cr2O4)2(OH2)2</SUB>]- complex ion in aqueous solutionscitations
- 2011Investigation of copper(II) complexation by glycylglycine using isothermal titration calorimetrycitations
- 2008Determination of dissociation constants for coordination compounds of Cr(III) and Co(III) using potentiometric and spectrophotometric methodscitations
Places of action
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article
Kinetics and thermodynamic of reaction of oxydiacetate copper(II) complex with 2,2′-bipyridine and 1,10-phenanthroline in anionic and cationic surfactant solutions
Abstract
The oxydiacetate complexes of copper(II) with 2,2′-bipyridine (bipy) and 1,10-phenanthroline (phen) have beeninvestigated towards their kinetic and thermodynamic stability. The kinetics of the substitution reactions of theoxydiacetate complex of Cu2+ with bipy and phen have been studied in two types of surfactant solutions - anionicdodecyl sulfate sodium (SDS) and cationic hexadecyl trimethyl-ammonium bromide (CTAB). The valuesof the observable rate constants for the studied reactions have been determined using the “Glint” program.Moreover,the thermodynamic stability of the copper(II) complexes with oda, phen and bipy in aqueous solutions hasbeen investigated using potentiometric titration method (PT). The concentration distributions of the studiedcomplexes as a function of pH calculated based on the values of log βpqrs have been determined. Additionally,the antioxidant activities of the oxydiacetate complexes of copper(II) with bipy and phen have been studiedby the nitro blue tetrazolium (NBT) test and the cyclic voltammetry (CV) technique.