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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Branco, Luís C.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)citations
- 2023Study of the mesomorphic properties and conductivity of n-alkyl-2-picolinium ionic liquid crystalscitations
- 2022Ferrocene-Based Porous Organic Polymer (FPOP): Synthesis, Characterization and an Electrochemical Studycitations
- 2022Synthesis and characterisation of ionic liquid crystals based on substituted pyridinium cationscitations
- 2020Application of polyoxometalate-ionic liquids (POM-ILs) in dye-sensitized solar cells (DSSCs)citations
- 2017Membranes with a low loading of Metal–Organic Framework-Supported Ionic Liquids for CO2/N2 separation in CO2 capturecitations
- 2015Characterization of a Novel Intrinsic Luminescent Room-Temperature Ionic Liquid Based on [P-6,P-6,P-6,P-14][ANS]citations
- 2015Electrochromic devices based on disubstituted oxo-bipyridinium ionic liquidscitations
- 2015Dipolar motions and ionic conduction in an ibuprofen derived ionic liquidcitations
- 2010Melting behaviour of ionic salts in the presence of high pressure CO2citations
- 2007Comparison of physicochemical properties of new ionic liquids based on imidazolium, quaternary ammonium, and guanidinium cationscitations
Places of action
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article
Application of polyoxometalate-ionic liquids (POM-ILs) in dye-sensitized solar cells (DSSCs)
Abstract
project “SunStorage- Harvesting and storage of solar energy”, with reference POCI-01-0145-FEDER-016387, and by national funds (PTDC/ QEQ-QFI/1971/2014), through FCT - Fundação para a Ciência e a Tecnologia. H. Cruz thanks to Fundacão para a Ciência e a Tecnologia, MCTES, for the norma transitória DL 57/2016 Program Contract. L. C. Branco thanks to financial support of FCT/MCTES IF/0041/2013/CP1161/CT00). Ana Lucia Pinto thanks to FCT/MCTES for the grant PD/BD/135087/2017 ; Polyoxometalates (POMs) as anionic metal oxides are promising candidates for application in dye-sensitized solar cells (DSSCs) due to their peculiar properties including a reversible and multi-electron redox behavior. In this work, four polyoxometalate as ionic liquids (POM-ILs) based on the combination between phosphomolybdate anion (PMo12O40 3−) and organic cations such as [BMIM]+, [BPy]+, [HDPy]+ and [P6,6,6,14]+ were prepared and characterized. A detailed chemical structural elucidation by elemental analysis, ATR-FTIR, 1H and 31P NMR spectroscopies have been performed. These POM-ILs were tested as photosensitizers by adsorption to the photoanode (TiO2 film) for different times (15 min to 17 h). The DSSCs performance can be highly improved comparing the commercially available compound and POM-ILs. The electrodeposition process is an excellent alternative to adsorption in order to improve the overall efficiencies. In general, [BPy]3[PMo12O40] and [P6,6,6,14]3[PMo12O40] are the most promissory compounds for DSSC approaches. ; publishersversion ; published