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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lima, João Carlos
Altice Portugal (Portugal)
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Cryoprotective Polysaccharides with Ordered Gel Structures Induce Ice Growth Anticipation and Survival Enhancement during Cell Cryopreservationcitations
- 2020Application of polyoxometalate-ionic liquids (POM-ILs) in dye-sensitized solar cells (DSSCs)citations
- 2017A non-invasive optical method for mapping temperature polarization in direct contact membrane distillationcitations
- 2016Molecular Weight Determination by Luminescent Chemo–enzymaticscitations
- 2015Tuning the Surface Chemistry of Nanoporous Carbons for Enhanced Nanoconfined Photochemical Activitycitations
- 2013Photoinduced reactions occurring on activated carbons. A combined photooxidation and ESR studycitations
- 2008Study of the effect of the phosphane bridging chain nature on the structural and photophysical properties of a series of gold(I) ethynylpyridine complexescitations
- 2008Probing the microenvironment of sol-gel entrapped cutinase: the role of added zeolite NaYcitations
- 2006Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)citations
- 2000Fluorescence-labeled pyrenesulfonamide response for characterizing polymeric interfaces in composite materialscitations
Places of action
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article
Application of polyoxometalate-ionic liquids (POM-ILs) in dye-sensitized solar cells (DSSCs)
Abstract
project “SunStorage- Harvesting and storage of solar energy”, with reference POCI-01-0145-FEDER-016387, and by national funds (PTDC/ QEQ-QFI/1971/2014), through FCT - Fundação para a Ciência e a Tecnologia. H. Cruz thanks to Fundacão para a Ciência e a Tecnologia, MCTES, for the norma transitória DL 57/2016 Program Contract. L. C. Branco thanks to financial support of FCT/MCTES IF/0041/2013/CP1161/CT00). Ana Lucia Pinto thanks to FCT/MCTES for the grant PD/BD/135087/2017 ; Polyoxometalates (POMs) as anionic metal oxides are promising candidates for application in dye-sensitized solar cells (DSSCs) due to their peculiar properties including a reversible and multi-electron redox behavior. In this work, four polyoxometalate as ionic liquids (POM-ILs) based on the combination between phosphomolybdate anion (PMo12O40 3−) and organic cations such as [BMIM]+, [BPy]+, [HDPy]+ and [P6,6,6,14]+ were prepared and characterized. A detailed chemical structural elucidation by elemental analysis, ATR-FTIR, 1H and 31P NMR spectroscopies have been performed. These POM-ILs were tested as photosensitizers by adsorption to the photoanode (TiO2 film) for different times (15 min to 17 h). The DSSCs performance can be highly improved comparing the commercially available compound and POM-ILs. The electrodeposition process is an excellent alternative to adsorption in order to improve the overall efficiencies. In general, [BPy]3[PMo12O40] and [P6,6,6,14]3[PMo12O40] are the most promissory compounds for DSSC approaches. ; publishersversion ; published