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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Amenitsch, Heinz
Graz University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (46/46 displayed)
- 2023Silicon and Germanium Functionalized Perylene Diimides – Synthesis, Optoelectronic Properties, and their Application as Non-Fullerene Acceptors in Organic Solar Cellscitations
- 2023Poly(ethylene oxide)-block-poly(hexyl acrylate) Copolymers as Templates for Large Mesopore Sizes─A Detailed Porosity Analysiscitations
- 2023Strongly Confined CsPbBr3 Quantum Dots as Quantum Emitters and Building Blocks for Rhombic Superlatticescitations
- 2023Lignin-Derived Mesoporous Carbon for Sodium-Ion Batteriescitations
- 2023Strongly Confined CsPbBr3 Quantum Dots as Quantum Emitters and Building Blocks for Rhombic Superlattices.
- 2023Solution-Processable Cu3BiS3 Thin Films: Growth Process Insights and Increased Charge Generation Properties by Interface Modificationcitations
- 2023The challenge with high permittivity acceptors in organic solar cells: a case study with Y-series derivativescitations
- 2023Strongly confined CsPbBr 3 quantum dots as quantum emitters and building blocks for rhombic superlatticescitations
- 2022Supramolecular Chalcogenâ€Bonded Semiconducting Nanoribbons at Work in Lighting Devicescitations
- 2022In Situ Study of Nanoporosity Evolution during Dealloying AgAu and CoPd by Grazing-Incidence Small-Angle X-ray Scatteringcitations
- 2022In Situ Study of Nanoporosity Evolution during Dealloying AgAu and CoPd by Grazing-Incidence Small-Angle X-ray Scatteringcitations
- 2022Supramolecular Chalcogen-Bonded Semiconducting Nanoribbons at Work in Lighting Devicescitations
- 2022Supramolecular Chalcogen-Bonded Semiconducting Nanoribbons at Work in Lighting Devicescitations
- 2022Glycol bearing perylene monoimide based non-fullerene acceptors with increased dielectric permittivitycitations
- 2022Self‐Assembly of Oriented Antibody‐Decorated Metal–Organic Framework Nanocrystals for Active‐Targeting Applicationscitations
- 2022Self‐Assembly of Oriented Antibody‐Decorated Metal–Organic Framework Nanocrystals for Active‐Targeting Applicationscitations
- 2021Block-Copolymers Enable Direct Reduction and Structuration of Noble Metal-based Filmscitations
- 2021Metal–Insulator Transition of Ultrathin Sputtered Metals on Phenolic Resin Thin Films: Growth Morphology and Relations to Surface Free Energy and Reactivitycitations
- 2021Monodisperse long-chain sulfobetaine-capped CsPbBr 3 nanocrystals and their superfluorescent assembliescitations
- 2021Self-Assembly of Oriented Antibody-Decorated Metal–Organic Framework Nanocrystals for Active-Targeting Applicationscitations
- 2021Perovskite-type superlattices from lead halide perovskite nanocubescitations
- 2021Two-dimensional perovskites with alternating cations in the interlayer space for stable light-emitting diodescitations
- 2020In situ electrochemical grazing incidence small angle X-ray scattering: From the design of an electrochemical cell to an exemplary study of fuel cell catalyst degradationcitations
- 2020Evolution of the PtNi Bimetallic Alloy Fuel Cell Catalyst under Simulated Operational Conditionscitations
- 2020Cellulose metal sulfide based nanocomposite thin films
- 2020Modulation of metal-azolate frameworks for the tunable release of encapsulated glycosaminoglycanscitations
- 2020Continuous-Flow Synthesis of ZIF-8 Biocomposites with Tunable Particle Sizecitations
- 2019INTERPLAY BETWEEN CRYSTAL STRUCTURE, SHAPE AND FUNCTIONALITY OF COLLOIDAL NANOCRYSTALS AND SUPERCRYSTALS
- 2019Encapsulation, Visualization and Expression of Genes with Biomimetically Mineralized Zeolitic Imidazolate Framework-8 (ZIF-8)citations
- 2019Stable ultraconcentrated and ultradilute colloids of CsPbX 3 (X=Cl, Br) nanocrystals using natural lecithin as a capping ligandcitations
- 2019Carbohydrates@MOFscitations
- 2018High Hydrostatic Pressure Induces a Lipid Phase Transition and Molecular Rearrangements in Low-Density Lipoprotein Nanoparticlescitations
- 2017Structural investigation of bulk and dispersed inverse lyotropic hexagonal liquid crystalline phases of eicosapentaenoic acid monoglyceridecitations
- 2016Design of broadband SERS substrates by the laser-induced aggregation of gold nanoparticlescitations
- 2014Order vs. disorder — a huge increase in ionic conductivity of nanocrystalline LiAlO2 embedded in an amorphous-like matrix of lithium aluminatecitations
- 2014Structural transitions in asymmetric poly(styrene)-block -poly(lactide) thin films induced by solvent vapor exposurecitations
- 2014Self-Assembly of Ferromagnetic Organic–Inorganic Perovskite-Like Filmscitations
- 2014Self-Assembly of Ferromagnetic Organic–Inorganic Perovskite-Like Filmscitations
- 2012Mesoporous SiO2 thin films containing photoluminescent ZnO nanoparticles and simultaneous SAXS/WAXS/ellipsometry experimentscitations
- 2009Hierarchical porous silica films with ultralow refractive indexcitations
- 2008Fabrication of mesoporous functionalized arrays by integrating deep X-ray lithography with dip-pen writingcitations
- 2007Time-resolved simultaneous detection of structural and chemical changes during self-assembly of mesostructured filmscitations
- 2007Highly ordered self-assembled mesostructured membranescitations
- 2005Thermal-induced phase transitions in self-assembled mesostructured films studied by small-angle X-ray scatteringcitations
- 2005Highly ordered "defect-free" self-assembled hybrid films with a tetragonal mesostructurecitations
- 2004Silica orthorhombic mesostructured films with low refractive index and high thermal stabilitycitations
Places of action
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article
Highly ordered self-assembled mesostructured membranes
Abstract
<p>Highly ordered silica and hybrid organic-inorganic membranes have been obtained through a slow and controlled solvent evaporation in the presence of a triblock copolymer as the structure-directing agent. Crack-free mesostructured membranes of large dimensions have been prepared. The mesophase is self-organized into a periodic cubic structure, Im over(3, ̄) m, and consists of macroscopic mesostructured domains that maintain the out-of-plane order throughout the material. After calcination at 350 °C the membranes remain transparent even though they break in fragments of some centimeters. Different techniques have been employed to characterize the mesoporous materials: small angle X-ray scattering (SAXS) using synchrotron radiation and transmission electron microscopy to study the porous structure, Fourier transform infrared spectroscopy (FTIR) in vacuum at different partial pressures to investigate the nature of the pore surface. SAXS analysis has been used to map the whole membrane, revealing some differences in the pore organization that can be attributed to a gradient in the evaporation rate. The infrared measurements at different partial pressures have elucidated the mechanism of water adsorption-desorption on the pore surface. The changes of the FTIR spectra with different partial pressure have demonstrated that the pore surface is covered by a layer of molecular water that is hydrogen bonded to silanol species.</p>