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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Neves, Ic
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2021Performance of self-cleaning cotton textiles coated with TiO2, TiO2-SiO2 and TiO2-SiO2-HY in removing Rhodamine B and Reactive Red 120 dyes from aqueous solutionscitations
- 2020Binuclear furanyl-azine metal complexes encapsulated in NaY zeolite as efficiently heterogeneous catalysts for phenol hydroxylationcitations
- 2019Photocatalytic performance of N-doped TiO(2)nano-SiO2-HY nanocomposites immobilized over cotton fabricscitations
- 2015Preparation and assessment of antimicrobial properties of bimetallic materials based on NaY zeolitecitations
- 2013Nanocomposites of poly(epsilon-caprolactone) doped with titanium speciescitations
- 2011Encapsulation of alpha-cyano-4-hydroxycinnamic acid into a NaY zeolitecitations
- 2011Stability of nanocomposites of poly(epsilon-caprolactone) with tungsten trioxidecitations
- 2010Enhancement of the Dielectric Constant and Thermal Properties of alpha-Poly(vinylidene fluoride)/Zeolite Nanocompositescitations
- 2009Redox properties of (1-(2-pyridylazo)-2-naphthol)copper(II) encapsulated in Y Zeolitecitations
- 2008Immobilization of Fe(III) complexes of pyridazine derivatives prepared from biosorbents supported on zeolitescitations
- 2008Organic-inorganic hybrid matrix doped with alkenyldiazenido complexes of molybdenumcitations
- 2004Synthesis and immobilization of molybdenum complexes in a pillared layered claycitations
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article
Synthesis and immobilization of molybdenum complexes in a pillared layered clay
Abstract
New molecular systems based on donor/acceptor groups connected by pi-conjugated bridge, trans-[MoF(NNC7H6SO2)-(Ph2PCH2CH2PPh2)(2)][BF4], have been synthesized. This complex with nonlinear optical (NLO) applications was immobilized by an adsorption process from liquid phase, in the interlayer of a pillared clay (PILC). The metal complex and the new materials were characterized by thermal analysis (DSC), chemical analysis, surface techniques (XPS), X-ray powder diffraction (XRD), nitrogen adsorption isotherms, spectroscopic methods (NMR, FT-IR and UV/Vis) and electrochemical measurements. The studies of the electrochemical and the spectroscopic properties of the complex show interactions between donor and acceptor groups across the conjugated bridge. The results obtained from the studies using different techniques of analysis confirm that the molybdenum complex was effectively immobilized in the host matrix and this process does not modify the morphology or structure of the PILC upon metal complex loading.