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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Pires, J.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2014Activated carbons prepared from industrial pre-treated cork: Sustainable adsorbents for pharmaceutical compounds removalcitations
- 2013Novel Composite Material Polyoxovanadate@MIL-101(Cr): A Highly Efficient Electrocatalyst for Ascorbic Acid Oxidationcitations
- 2013Alkene epoxidation by manganese(III) complexes immobilized onto nanostructured carbon CMK-3citations
- 2012Oxidovanadium(IV) acetylacetonate immobilized onto CMK-3 for heterogeneous epoxidation of geraniolcitations
- 2011Epoxidation of olefins catalyzed by manganese(III) salen complexes grafted to porous heterostructured clayscitations
- 2010Templated synthesis of carbon materials mediated by porous clay heterostructurescitations
- 2005Fatigue damage analysis of aluminised glass fibre compositescitations
- 2004Synthesis and immobilization of molybdenum complexes in a pillared layered claycitations
Places of action
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article
Synthesis and immobilization of molybdenum complexes in a pillared layered clay
Abstract
New molecular systems based on donor/acceptor groups connected by pi-conjugated bridge, trans-[MoF(NNC7H6SO2)-(Ph2PCH2CH2PPh2)(2)][BF4], have been synthesized. This complex with nonlinear optical (NLO) applications was immobilized by an adsorption process from liquid phase, in the interlayer of a pillared clay (PILC). The metal complex and the new materials were characterized by thermal analysis (DSC), chemical analysis, surface techniques (XPS), X-ray powder diffraction (XRD), nitrogen adsorption isotherms, spectroscopic methods (NMR, FT-IR and UV/Vis) and electrochemical measurements. The studies of the electrochemical and the spectroscopic properties of the complex show interactions between donor and acceptor groups across the conjugated bridge. The results obtained from the studies using different techniques of analysis confirm that the molybdenum complex was effectively immobilized in the host matrix and this process does not modify the morphology or structure of the PILC upon metal complex loading.