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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Céspedes, Francisco
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2016Characterization protocol to improve the electroanalytical response of graphene-polymer nanocomposite sensorscitations
- 2016Highly sensitive electrochemical immunosensor for IgG detection based on optimized rigid biocompositescitations
- 2016Amperometric thyroxine sensor using a nanocomposite based on graphene modified with gold nanoparticles carrying a thiolated β-cyclodextrincitations
- 2016Intermatrix Synthesis as a rapid, inexpensive and reproducible methodology for the in situ functionalization of nanostructured surfaces with quantum dotscitations
- 2016CdS quantum dots as a scattering nanomaterial of carbon nanotubes in polymeric nanocomposite sensors for microelectrode array behaviorcitations
- 2016Intermatrix synthesis of Ag, AgAu and Au nanoparticles by the galvanic replacement strategy for bactericidal and electrocatalytically active nanocompositescitations
- 2015Modified multiwalled carbon nanotube/epoxy amperometric nanocomposite sensors with CuO nanoparticles for electrocatalytic detection of free chlorinecitations
- 2015Improvement of the detection limit for biosensors: Advances on the optimization of biocomposite compositioncitations
- 2015Effect of carbon nanotubes purification on electroanalytical response of near-percolation amperometric nanocomposite sensorscitations
- 2014Towards to the improvement of the analytical response in voltammetric sensors based on rigid compositescitations
- 2014Simple green routes for the customized preparation of sensitive carbon nanotubes/epoxy nanocomposite electrodes with functional metal nanoparticlescitations
- 2012Determination of total polyphenol index in wines employing a voltammetric electronic tonguecitations
- 2011A new amperometric bienzymatic biosensor based on biocomposites for the determination of gluconic acid in winescitations
- 2009Novel amperometric sensor based on rigid near-percolation compositecitations
- 2009Resolution of heavy metal mixtures from highly overlapped ASV voltammograms employing a wavelet neural networkcitations
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article
Modified multiwalled carbon nanotube/epoxy amperometric nanocomposite sensors with CuO nanoparticles for electrocatalytic detection of free chlorine
Abstract
© 2015 Elsevier B.V. The benefit of using copper (II) oxide nanoparticles (CuO-NPs), which have catalytic activity for the decomposition of hypochlorite solutions, for the amperometric detection of free chlorine is reported. Cyclic voltammetry and electrochemical impedance spectroscopy have been applied for the electrochemical characterization of nanocomposite materials. If the amperometric detection of free chlorine was determined previously using multiwall carbon nanotube (MWCNT) based epoxy nanocomposite sensors, the electrocatalytic reduction of hypochlorite using modified MWCNT/epoxy nanocomposite sensors with CuO-NPs to obtain sensitive devices capable to amperometrically determine traces of free chlorine in water is demonstrated here. The CuO-NPs were incorporated in the nanocomposite electrode in two different ways i) on the MWCNT surface, Route A and ii) in the nanocomposite matrix in powder form, Route B. Both modified-nanocomposite sensors have shown a fast electron transfer exchange, high electroactive area and an enhancement on the electroanalytical signal. Accordingly, a greater sensitivity compared to raw MWCNT/epoxy nanocomposite sensors has been observed, obtaining the lowest limit of detection for the CuO-NPs modified nanocomposite sensors obtained by Route B.