| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Rauf, Sajid
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Highly Active Interfacial Sites in SFT-SnO2 Heterojunction Electrolyte for Enhanced Fuel Cell Performance via Engineered Energy Bands: Envisioned Theoretically and Experimentallycitations
- 2024Boosting the electrochemical performance of oxygen electrodes via the formation of LSCF-BaCe 0.9–x Mo x Y 0.1 O 3–δ triple conducting composite for solid oxide fuel cells:Part IIcitations
- 2024Boosting the electrochemical performance of oxygen electrodes via the formation of LSCF-BaCe0.9–xMoxY0.1O3–δ triple conducting composite for solid oxide fuel cellscitations
- 2023Enabling high ionic conductivity in semiconductor electrolyte membrane by surface engineering and band alignment for LT-CFCscitations
- 2023Enabling high ionic conductivity in semiconductor electrolyte membrane by surface engineering and band alignment for LT-CFCscitations
- 2023Highly Active Interfacial Sites in <scp>SFT‐SnO<sub>2</sub></scp> Heterojunction Electrolyte for Enhanced Fuel Cell Performance via Engineered Energy Bands: Envisioned Theoretically and Experimentallycitations
- 2022Demonstrating the potential of iron-doped strontium titanate electrolyte with high-performance for low temperature ceramic fuel cellscitations
- 2022Perovskite Al-SrTiO<sub>3</sub> semiconductor electrolyte with superionic conduction in ceramic fuel cellscitations
- 2022Perovskite Al-SrTiO3 semiconductor electrolyte with superionic conduction in ceramic fuel cellscitations
- 2022Improved self-consistency and oxygen reduction activity of CaFe2O4 for protonic ceramic fuel cell by porous NiO-foam supportcitations
- 2022Nitrogenized 2D Covalent Organic Framework Decorated Ni‐Rich Single Crystal Cathode to Ameliorate the Electrochemical Performance of Lithium Batteriescitations
- 2021Semiconductor Nb-Doped SrTiO3-δPerovskite Electrolyte for a Ceramic Fuel Cellcitations
- 2021Interface engineering of bi-layer semiconductor SrCoSnO3-δ-CeO2-δ heterojunction electrolyte for boosting the electrochemical performance of low-temperature ceramic fuel cellcitations
- 2021Tailoring triple charge conduction in BaCo0.2Fe0.1Ce0.2Tm0.1Zr0.3Y0.1O3−δ semiconductor electrolyte for boosting solid oxide fuel cell performancecitations
- 2021Novel Perovskite Semiconductor Based on Co/Fe-Codoped LBZY (La0.5Ba0.5Co0.2Fe0.2Zr0.3Y0.3O3-δ) as an Electrolyte in Ceramic Fuel Cellscitations
- 2021Electrochemical Properties of a Dual-Ion Semiconductor-Ionic Co0.2Zn0.8O-Sm0.20Ce0.80O2-δComposite for a High-Performance Low-Temperature Solid Oxide Fuel Cellcitations
- 2021Promoted electrocatalytic activity and ionic transport simultaneously in dual functional Ba0.5Sr0.5Fe0.8Sb0.2O3-δ-Sm0.2Ce0.8O2-δ heterostructurecitations
- 2020Semiconductor Fe-doped SrTiO3-δ perovskite electrolyte for low-temperature solid oxide fuel cell (LT-SOFC) operating below 520 °Ccitations
Places of action
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article
Enabling high ionic conductivity in semiconductor electrolyte membrane by surface engineering and band alignment for LT-CFCs
Abstract
Wide bandgap semiconductor perovskite SrTiO3 (STO) has attracted extensive attention due to its higher kinetics of electrons (electronic conductivity). However, rare studies have been performed to tune the STO semiconductor towards ionic conduction, which could make it a promising candidate for an electrolyte in ceramic fuel cells (CFCs). Herein, we have designed a semiconductor perovskite Co/Fe–SrTiO3 as an electrolyte membrane to tune its semiconducting property to the ionic conduction via surface-enriched O-vacancies. The surface doping of Co/Fe into SrTiO3 resulted in lowering the Fermi level, leading to the space charge region and local electric field on the surficial region, which can enhance the ionic conduction (proton conduction) at the surface. The designed electrolyte exhibited a high ionic conductivity of 0.19 S/cm and the fuel cell employing it delivered a maximum power density of 1016 mW/cm2 at 520 °C. Moreover, the theoretical calculation was performed to support the experimental results, like disorder in lattice and oxygen vacancy formation energy. The surface doping of Co/Fe facilitated the enriched surface channels for quick ion transportation with lower activation energy. The presented methodology of surface doping has proven to be suitable for designing advanced materials for wide bandgap semiconductors with high ionic conductivity to develop next-generation CFCs.