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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mattia, Davide
University of Bath
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2021Hydrophobic poly(vinylidene fluoride) / siloxene nanofiltration membranescitations
- 2021Hydrophobic poly(vinylidene fluoride) / siloxene nanofiltration membranescitations
- 2020High flux thin-film nanocomposites with embedded boron nitride nanotubes for nanofiltrationcitations
- 2020High flux thin-film nanocomposites with embedded boron nitride nanotubes for nanofiltrationcitations
- 2019Surface-controlled water flow in nanotube membranescitations
- 2019Surface-controlled water flow in nanotube membranescitations
- 2018Bean seedling growth enhancement using magnetite nanoparticlescitations
- 2014ZnO Nanostructured photo-catalytic films obtained by anodization and its application in the degradation of organic pollutants
- 2010Water transport through nanoporous materialscitations
- 2006Effect of Graphitization on the Wettability and Electrical Conductivity of CVD-Carbon Nanotubes and Films
- 2006Filling carbon nanopipes with functional nanoparticles
- 2005Wetting of HIP AlN-TiB2 ceramic composites by liquid metals and alloys
- 2005Oxidation behaviour of an aluminium nitride-hafnium diboride ceramic composite
Places of action
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article
Hydrophobic poly(vinylidene fluoride) / siloxene nanofiltration membranes
Abstract
<p>Hydrophobic, chemically resistant nanofiltration (NF) polymeric membranes could provide major improvements to a wide range of processes, from pharmaceutical manufacturing to hazardous waste treatment. Here, we report the fabrication of the first poly (vinylidene fluoride) (PVDF) NF membranes retaining their hydrophobicity and surface chemistry. This was achieved by incorporating in the polymer 2D siloxene, which induce a compaction of the PVDF chains, resulting in low free volume and a highly ordered microstructure. Siloxene nanosheets were obtained from deintercalation of Ca from CaSi<sub>2</sub> using HCl, followed by exfoliation and size fractionation, with average lateral dimension of 1–2 μm and thickness of 3–4 nm. The resulting membranes, containing 0.075 wt% of siloxene, have a pure water permeance of 22 ± 2 L m<sup>-2</sup> h<sup>-1</sup> bar<sup>-1</sup> and molecular weight cut-off (MWCO) of 530 Da. The same membrane also showed stable hexane permeance of 11 L m<sup>-2</sup> h<sup>-1</sup> bar<sup>-1</sup> for 24 h with MWCO of around 535 Da. These results supersede the performance of commercial NF membranes, expanding the potential application of nanofiltration to processes requiring stable, chemically resistant and hydrophobic nanofiltration membranes.</p>