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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cseri, Levente
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Topics
Publications (14/14 displayed)
- 2024Tunable 2D Conjugated Porous Organic Polymer Films for Precise Molecular Nanofiltration and Optoelectronicscitations
- 2021Electrospun Adsorptive Nanofibrous Membranes from Ion Exchange Polymers to Snare Textile Dyes from Wastewatercitations
- 2021Electrospun Adsorptive Nanofibrous Membranes from Ion Exchange Polymers to Snare Textile Dyes from Wastewatercitations
- 2020Metal–Organic Frameworks (MOFs) and MOF-Derived Porous Carbon Materials for Sustainable Adsorptive Wastewater Treatment
- 2020Asymmetric Membrane Capacitive Deionization using Anion-Exchange Membranes based on Quaternized Polymer Blendscitations
- 2020Asymmetric Membrane Capacitive Deionization using Anion-Exchange Membranes based on Quaternized Polymer Blendscitations
- 2020Graphene–PSS/L-DOPA nanocomposite cation exchange membranes for electrodialysis desalinationcitations
- 2020Graphene–PSS/L-DOPA nanocomposite cation exchange membranes for electrodialysis desalinationcitations
- 2019Electrostatically-coupled graphene oxide nanocomposite cation exchange membranecitations
- 2019Electrostatically-coupled graphene oxide nanocomposite cation exchange membranecitations
- 2018Robust Covalently Crosslinked Polybenzimidazole/Graphene Oxide Membranes for High-Flux Organic Solvent Nanofiltrationcitations
- 2018Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysiscitations
- 2018Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysiscitations
- 2018Robust Covalently Cross-linked Polybenzimidazole/Graphene Oxide Membranes for High-Flux Organic Solvent Nanofiltrationcitations
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article
Electrostatically-coupled graphene oxide nanocomposite cation exchange membrane
Abstract
We report the preparation of an electrostatically-coupled graphene oxide nanocomposite cation exchange membrane (CEM) based on sulfonic group containing graphene oxide (SGO) (45 wt. % loading) and polyvinylidene fluoride (PVDF), where the ion exchange groups were provided by the SGO additive. SGO was prepared via the mixing of graphene oxide (GO) with a mixture derived from 3,4-dihydroxy-L-phenylalanine (L-DOPA) and poly(sodium 4-styrenesulfonate) (PSS). A mold-casting technique was developed to fabricate the free-standing nanocomposite CEM. The presence of sulfonic groups in the nanocomposite was confirmed with FTIR spectroscopy. Energy dispersive spectroscopy analysis showed the SGO was distributed across the entire membrane matrix, with minimal aggregation. Incorporation of SGO into the polymer matrix resulted in notable increases in the membrane surface charge. The resultant SGO/PVDF nanocomposite CEM membrane demonstrated high hydrophilicity and high water uptake, but low swelling ratio. Furthermore, evaluation of the electrochemical properties of the nanocomposite CEM showed favorable ion exchange capacity (0.63 ± 0.08 meq/g), permselectivity (0.95 ± 0.04), and area resistance (2.8 ± 0.2 Ω cm2). The nanocomposite CEM show good potential for use in electromembrane desalination applications.