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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Holmes, Stuart
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Water cluster characteristics of fuel cell gas diffusion layers with artificial microporous layer crack dilationcitations
- 2022Porous silica nanosheets in PIM-1 membranes for CO 2 separationcitations
- 2022Porous silica nanosheets in PIM-1 membranes for CO2 separationcitations
- 2022Thin film nanocomposite membranes of PIM-1 and graphene oxide/ZIF-8 nanohybrids for organophilic pervaporationcitations
- 2022Thin film nanocomposite membranes of PIM-1 and graphene oxide/ZIF-8 nanohybrids for organophilic pervaporationcitations
- 2021High–performance polymer electrolyte membranes incorporated with 2D silica nanosheets in high–temperature proton exchange membrane fuel cells
- 2018Study on the formation of thin film nanocomposite (TFN) membranes of polymers of intrinsic microporosity and graphene-like fillers: effect of lateral flake size and chemical functionalizationcitations
- 2018Study on the formation of thin film nanocomposite (TFN) membranes of polymers of intrinsic microporosity and graphene-like fillers: effect of lateral flake size and chemical functionalizationcitations
- 2018Flux-enhanced PVDF mixed matrix membranes incorporating APTS-functionalized graphene oxide for membrane distillationcitations
- 2017Mordenite/Nafion and Analcime/Nafion Composite Membranes Prepared by Spray Method for Improved Direct Methanol Fuel Cell Performancecitations
- 2016Surface Modification of Mordenite in Nafion Composite Membrane for Direct Ethanol Fuel Cell and Its Characterizations: Effect of Types of Silane Coupling Agentcitations
- 2013Supercapacitance from cellulose and carbon nanotube nanocomposite fiberscitations
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article
Study on the formation of thin film nanocomposite (TFN) membranes of polymers of intrinsic microporosity and graphene-like fillers: effect of lateral flake size and chemical functionalization
Abstract
Thin film nanocomposite (TFN) membranes of polymer of intrinsic microporosity PIM-1 incorporating graphene oxide (GO) nanosheets of different sizes and chemistries are presented. These membranes show an improved separation performance for the recovery of n-butanol from aqueous solutions through pervaporation; an improvement of ca. a third of the value achieved for pristine PIM-1 thin films is obtained for TFN membranes filled with nanometer-sized reduced octyl-functionalized GO. In addition, these nanometer-sized fillers lead to a maximum increase in total flux of approximately 40%. The thickness of the supported films is in the range 1–1.5 µm, and fillers used are micrometer- and nanometer-sized alkyl-functionalized GO nanosheets and their chemically reduced counterparts. As evidenced by a superior overall membrane performance, the interfacial interaction between the filler and the polymer matrix is enhanced for those whose lateral size is in the nanometer range. Moreover, an enhancement in the separation performance and productivity of such membranes is observed for higher operating temperatures and higher contents of n-butanol in the feed.