| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mecerreyes, David
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2024Piperazinium Poly(Ionic Liquid)s as Solid Electrolytes for Lithium Batteriescitations
- 2024Light-Based 3D Multi-Material Printing of Micro-Structured Bio-Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics.
- 2024Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronicscitations
- 2023Dual redox-active porous polyimides as high performance and versatile electrode material for next-generation batteriescitations
- 2022Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectorscitations
- 2022Fast Visible-Light Photopolymerization in the Presence of Multiwalled Carbon Nanotubes: Toward 3D Printing Conducting Nanocompositescitations
- 2020Toward High‐Energy‐Density Lithium Metal Batteries: Opportunities and Challenges for Solid Organic Electrolytescitations
- 2020Tuning the properties of a UV-polymerized, cross-linked solid polymer electrolyte for lithium batteriescitations
- 2020Influence of the cyclic vs. linear carbonate segments in the properties and performance of CO2-sourced polymer electrolytes for lithium batteriescitations
- 2018Biodegradable Polycarbonate Iongels for Electrophysiology Measurements.
- 2018Three-Dimensional conductive scaffolds as neural prostheses based on carbon nanotubes and polypyrrolecitations
- 2018Mixing poly(ionic liquid)s and ionic liquids with different cyano anionscitations
- 2018New electroactive macromonomers and multi-responsive PEDOT graft copolymerscitations
- 2017Novel Lithium Battery Single-Ion Block Copolymer Electrolytes based on Poly(Ethylene Oxide) and Methacrylic Sulfonamide
- 2017New Families of Single-Ion Block Copolymer Electrolytes based on Poly(Ethylene Oxide) and Methacrylic Sulfonamide for Lithium Batteries
- 2017Effect of the fullerene in the properties of thin PEDOT/C60films obtained by co-electrodepositioncitations
- 2017Preparation and characterization of gel polymer electrolytes using poly(ionic liquids) and high lithium salt concentration ionic liquidscitations
- 2014Post-polymerization modification and organocatalysis using reactive statistical poly(ionic liquid)-based copolymerscitations
- 2013Polymeric ionic liquids with mixtures of counter-anions: a new straightforward strategy for designing pyrrolidinium-based CO2 separation membranescitations
- 2010Parylene nanocomposites using modified magnetic nanoparticlescitations
- 2007Structure and properties of a semifluorinated diblock copolymer modified epoxy blendcitations
- 2000Ring-Opening Polymerization of γ-bromo-ε-caprolactone : A novel route to functionalized aliphatic polyesterscitations
- 2000Ring-opening polymerization of 6-hydroxynon-8-enoic acid lactone : Novel biodegradable copolymers containing allyl pendent groups
- 2000First example of an unsymmetrical difunctional monomer polymerizable by two living/controlled methods
Places of action
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article
Mixing poly(ionic liquid)s and ionic liquids with different cyano anions
Abstract
<p>In this work, poly(ionic liquid)–ionic liquid (PIL–IL) composite membranes were prepared using the solvent casting technique. The studied PILs have pyrrolidinium polycation backbone ([Pyr<sub>11</sub>]<sup>+</sup>), while the five ILs display either an imidazolium ([C<sub>2</sub>mim]<sup>+</sup>) or a pyrrolidinium ([Pyr<sub>14</sub>]<sup>+</sup>) based cation. Both the PIL and IL components comprised cyano-functionalized anions ([N(CN)<sub>2</sub>]<sup>–</sup>, [C(CN)<sub>3</sub>]<sup>–</sup> or [B(CN)<sub>4</sub>]<sup>–</sup>), being the anion for each component different from one another. The use of the [NTf<sub>2</sub>]<sup>–</sup> anion was also tested for comparison. Several experimental conditions for the solvent casting procedure were tested in order to prepare homogenous and free standing PIL–IL composite membranes. The CO<sub>2</sub> and N<sub>2</sub> permeation properties (permeability, diffusivity and solubility) were evaluated at a fixed temperature (293 K) and constant trans-membrane pressure differential (100 kPa) using a time-lag apparatus, so that trends regarding the different anions either on the PIL or IL could be obtained and evaluated. From all 42 PIL–IL combinations tested, 21 were suitable membranes (homogeneous and free standing) for gas permeation experiments and 4 of them were on top or surpassed the 2008 Robeson upper bound for CO<sub>2</sub>/N<sub>2</sub> separation. The best performance membranes contain the [C(CN)<sub>3</sub>]<sup>–</sup> and [B(CN)<sub>4</sub>]<sup>–</sup> anions, enlightening therefore the promise these anions entail for future high performance membranes for post-combustion CO<sub>2</sub> separation.</p>