| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Gorgojo, Patricia
Universidad de Zaragoza
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (26/26 displayed)
- 2024Mixed matrix and thin-film nanocomposite membranes of PIM-1 and hydrolyzed PIM-1 with Ni- and Co-MOF-74 nanoparticles for CO 2 separation: Comparison of blending, grafting and crosslinking fabrication methodscitations
- 2024Mixed matrix and thin-film nanocomposite membranes of PIM-1 and hydrolyzed PIM-1 with Ni- and Co-MOF-74 nanoparticles for CO2 separation: Comparison of blending, grafting and crosslinking fabrication methodscitations
- 2024Spray coating of 2D materials in the production of antifouling membranes for membrane distillationcitations
- 2024High gas permeability in aged superglassy membranes with nanosized UiO-66−NH2/cPIM-1 network fillerscitations
- 2023Organic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from watercitations
- 2023Organic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from watercitations
- 2023CO2 separation using thin film composite membranes of acid-hydrolyzed PIM-1citations
- 2022Porous silica nanosheets in PIM-1 membranes for CO 2 separationcitations
- 2022Porous silica nanosheets in PIM-1 membranes for CO2 separationcitations
- 2022Thin film nanocomposite membranes of superglassy PIM-1 and amine-functionalised 2D fillers for gas separationcitations
- 2022Thin film nanocomposite membranes of PIM-1 and graphene oxide/ZIF-8 nanohybrids for organophilic pervaporationcitations
- 2022Thin film nanocomposite membranes of PIM-1 and graphene oxide/ZIF-8 nanohybrids for organophilic pervaporationcitations
- 2021PIM-1/Holey Graphene Oxide Mixed Matrix Membranes for Gas Separation: Unveiling the Role of Holescitations
- 2021POSS-Functionalized Graphene Oxide/PVDF Electrospun Membranes for Complete Arsenic Removal Using Membrane Distillationcitations
- 2020The use of carbon nanomaterials in membrane distillation membranes: a review
- 2020Superglassy Polymers to Treat Natural Gas by Hybrid Membrane/Amine Processes: Can Fillers Help?citations
- 2020Functionalized graphene-based polyamide thin film nanocomposite membranes for organic solvent nanofiltrationcitations
- 2018Study on the formation of thin film nanocomposite (TFN) membranes of polymers of intrinsic microporosity and graphene-like fillers: effect of lateral flake size and chemical functionalizationcitations
- 2018Study on the formation of thin film nanocomposite (TFN) membranes of polymers of intrinsic microporosity and graphene-like fillers: effect of lateral flake size and chemical functionalizationcitations
- 2018Impeded physical aging in PIM-1 membranes containing graphene-like fillerscitations
- 2018Flux-enhanced PVDF mixed matrix membranes incorporating APTS-functionalized graphene oxide for membrane distillationcitations
- 2017Enhanced organophilic separations with mixed matrix membranes of polymers of intrinsic microporosity and graphene-like fillerscitations
- 2016Synthesis and characterization of composite membranes made of graphene and polymers of intrinsic microporositycitations
- 2014Ultrathin polymer films with intrinsic microporosity: Anomalous solvent permeation and high flux membranescitations
- 2013High flux thin film nanocomposite membranes based on metal-organic frameworks for organic solvent nanofiltrationcitations
- 2010Exfoliated titanosilicate material UZAR-S1 obtained from JDF-L1citations
Places of action
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article
Enhanced organophilic separations with mixed matrix membranes of polymers of intrinsic microporosity and graphene-like fillers
Abstract
Organophilic mixed matrix membranes (MMMs) have been fabricated with the polymer of intrinsic microporosity PIM-1 and graphene oxide (GO) derivatives for the recovery of 1-butanol and ethanol from aqueous solutions via pervaporation (PV). Graphene oxide (GO) has been synthesized in solution through a modified Hummers’ method, functionalized with alkylamines, and further reduced. The use of two alkylamines with chains of different lengths, octylamine (OA) and octadecylamine (ODA) −8 and 18 carbons, respectively - has been evaluated and the functionalized GO materials have been used as fillers in MMMs. The membranes have been prepared by casting-solvent evaporation of PIM-1/GO derivative solutions at room temperature, and a range of characterization techniques have been used to interpret their structure and relate it to their separation performance. Electron microscopy has been carried out to determine the morphology of the membranes and the dispersion of the functionalized GO flakes in the polymer matrix. Moreover, the membranes have been characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and contact angle. Separation of alcohol from two binary mixtures composed of ethanol (EtOH)/water and butanol (BtOH)/water, containing 5 wt% of alcohol, have been performed. Under these conditions, the incorporation of graphene-like fillers at relatively low concentrations shows an increase in average separation factor for butanol (βBtOH/H2O) from 13.5 for pure PIM-1 membranes to, in some cases, more than double for the MMMs; with the addition of 0.1 wt% of reduced amine-functionalized GO βBtOH/H2O reaches 32.9 and 26.9 for the short-chain (OA) and the long-chain (ODA) alkylamines, respectively.