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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Foghmoes, Søren Preben Vagn
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2020Surface treatments and functionalization of metal‐ceramic membranes for improved enzyme immobilization performancecitations
- 2018Citrate- and glycerol triesters as novel dual-functional dispersants and plasticisers for ceramic processingcitations
- 2017Development of redox stable, multifunctional substrates for anode supported SOFCS
- 2016Complementary analysis techniques applied on optimizing suspensions of yttria stabilized zirconiacitations
- 2016Design and optimization of porous ceramic supports for asymmetric ceria-based oxygen transport membranescitations
- 2016Design and optimization of porous ceramic supports for asymmetric ceria-based oxygen transport membranescitations
- 2016Novel ceramic processing method for substitution of toxic plasticizerscitations
- 2014Densification and grain growth kinetics of Ce 0.9 Gd 0.1 O 1.95 in tape cast layers: The influence of porositycitations
- 2014In situ characterization of delamination and crack growth of a CGO–LSM multi-layer ceramic sample investigated by X-ray tomographic microscopycitations
- 2014Densification and grain growth kinetics of Ce0.9Gd0.1O1.95 in tape cast layers: The influence of porositycitations
- 2013Sintering process optimization for multi-layer CGO membranes by in situ techniquescitations
- 2013The effect of forming stresses on the sintering of ultra-fine Ce0.9Gd0.1O2-δ powderscitations
- 2012Durable and Robust Solid Oxide Fuel Cells
- 2011Evaluation of thin film ceria membranes for syngas membrane reactors—Preparation, characterization and testingcitations
- 2011On the use of supported ceria membranes for oxyfuel process/syngas productioncitations
Places of action
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article
Design and optimization of porous ceramic supports for asymmetric ceria-based oxygen transport membranes
Abstract
The microstructure, mechanical properties and gas permeability of porous supports of Ce<sub>0.9</sub>Gd<sub>0.1</sub>O<sub>1.95−δ</sub> (CGO) were investigated as a function of sintering temperature and volume fraction of pore former for use in planar asymmetric oxygen transport membranes (OTMs). With increasing the pore former content from 11 vol% to 16 vol%, the gas permeabilities increased by a factor of 5 when support tapes were sintered to comparable densities. The improved permeabilities were due to a more favourable microstructure with larger interconnected pores at a porosity of 45% and a fracture strength of 47±2 MPa (m=7). The achieved gas permeability of 2.25×10<sup>−15</sup> m<sup>2</sup> for a 0.4 mm thick support will not limit the gas transport for oxygen production but in partial oxidation of methane to syngas at higher oxygen fluxes. For integration of the CGO support layer into a flat, asymmetric CGO membrane, the sintering activity of the CGO membrane was reduced by Fe<sub>2</sub>O<sub>3</sub> addition (replacing Co<sub>3</sub>O<sub>4</sub> as sintering additive).