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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wessling, Matthias
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (35/35 displayed)
- 2024Electro‐Conductive Ti<sub>3</sub>C<sub>2</sub> MXene Multilayered Membranes: Dye Removal and Antifouling Performancecitations
- 2024Tubular and bio-based carbons as binder-free gas diffusion electrodes for heterogeneous electro-Fenton to remove micropollutantscitations
- 2023Tailoring Pore Networks – Gas Diffusion Electrodes via Additive Manufacturingcitations
- 2023Poly(aryl ether ketone) hollow fibers preparation with acid resistant spinneretscitations
- 2022Monolithic SiC supports with tailored hierarchical porosity for molecularly selective membranes and supported liquid-phase catalysiscitations
- 2022Monolithic SiC supports with tailored hierarchical porosity for molecularly selective membranes and supported liquid-phase catalysiscitations
- 2022On the Mixed Gas Behavior of Organosilica Membranes Fabricated by Plasma-Enhanced Chemical Vapor Deposition (PECVD)citations
- 2022Rotating microstructured spinnerets produce helical ridge membranes to overcome mass transfer limitationscitations
- 2022Organosilica coating layer prevents aging of a polymer with intrinsic microporositycitations
- 2020Stimuli-Responsive Zwitterionic Core-Shell Microgels for Antifouling Surface Coatingscitations
- 2020Tubular hollow fibre electrodes for CO2 reduction made from copper aluminum alloy with drastically increased intrinsic porosity
- 2020Steady-state electrochemical synthesis of HKUST-1 with polarity reversalcitations
- 2019High-Throughput Production of Micrometer Sized Double Emulsions and Microgel Capsules in Parallelized 3D Printed Microfluidic Devices
- 2019Layer-by-layer membrane modification allows scandium recovery by nanofiltrationcitations
- 2013Conjugated polymer particles : Towards self-assembling organic photonics
- 2013Challenges and advances in the field of self-assembled membranescitations
- 2012Fabrication of cell container arrays with overlaid surface topographiescitations
- 2012Fabrication of cell container arrays with overlaid surface topographiescitations
- 2012Towards a generic method for inorganic porous hollow fibers preparation with shrinkage-controlled small radial dimensions, applied to Al2O3, Ni, SiC, stainless steel, and YSZcitations
- 2011Hollow fiber ultrafiltration membranes with microstructured inner skincitations
- 2011Porous stainless steel hollow fiber membranes via dry-wet spinningcitations
- 2011Carbon nanofibers in catalytic membrane microreactorscitations
- 2011Thermoforming of film-based biomedical microdevicescitations
- 2011Porous stainless steel hollow fibers with shrinkage-controlled small radial dimensionscitations
- 2010Microstructured hollow fibers for ultrafiltrationcitations
- 2010Shrinkage effects during polmer phase separation on microfabricated moldscitations
- 2010Surface texturing inside ceramic macro/micro channelscitations
- 2010Polymeric microsieves via phase separation microfabricationcitations
- 2009Microcontact Printing of Dendrimers, Proteins, and Nanoparticles by Porous Stampscitations
- 2009Micropatterned polymer films by vapor-induced phase separation using permeable moldscitations
- 2007Morphology and Microtopology of Cation-Exchange Polymers and the Origin of the Overlimiting Currentcitations
- 2006Polymeric microsieves produced by phase separation micromoldingcitations
- 2006Fullerene-modified poly(2,6-dimethyl-1,4-phenylene oxide) gas separation membranes: Why binding is better than dispersing
- 2006Superhydrophobic Surfaces Having Two-Fold Adjustable Roughness Prepared in a Single Stepcitations
- 2005New replication technique for the fabrication of thin polymeric microfluidic devices with tunable porositycitations
Places of action
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article
Towards a generic method for inorganic porous hollow fibers preparation with shrinkage-controlled small radial dimensions, applied to Al2O3, Ni, SiC, stainless steel, and YSZ
Abstract
A versatile method is presented for the preparation of porous inorganic hollow fibers with small tunable radial dimensions, down to ∼250 μm outer diameter. The approach allows fabrication of thin hollow fibers of various materials, as is demonstrated for alumina, nickel, silicon carbide, stainless steel, and yttria stabilized zirconia. The preparation method is based on dry-wet spinning of a particle-loaded polymer solution followed by thermal treatment. Exceptionally small radial dimensions have been achieved by surface energy driven viscous flow of the green fiber, resulting in a reduction of macro-void volume. It is shown that the extent of viscous deformation is directly related to the rheology of the particle-loaded green fiber above the glass transition temperature of the polymer. A particle specific limited concentration range can be identified in which viscous deformation is possible. Above a critical particle volume fraction the viscosity of the particle–polymer material increases sharply and the time scale of viscous deformation becomes too long. Below a minimum concentration of particles it is not possible to sinter the particles together. For small particles of alumina, silicon carbide, and yttria stabilized zirconia the concentration range allowing viscous deformation is very narrow as compared to that of larger metal particles.