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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lefferts, Leon
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2023Modelling of the catalytic initiation of methane coupling under non-oxidative conditionscitations
- 2022Enhanced catalytic activity and stability of nanoshaped Ni/CeO2 for CO2 methanation in micro-monolithscitations
- 2022Enhanced catalytic activity and stability of nanoshaped Ni/CeO2 for CO2 methanation in micro-monolithscitations
- 2018Non-oxidative methane coupling to C2 hydrocarbons in a microwave plasma reactorcitations
- 2016Carbon Nanofibers Grown on Large Woven Cloths: Morphology and Properties of Growthcitations
- 2015Synthesis of Carbon Nanofibers on Large Woven Clothcitations
- 2011Carbon nanofibers in catalytic membrane microreactorscitations
Places of action
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article
Carbon nanofibers in catalytic membrane microreactors
Abstract
In this study, we report on the fabrication and operation of new hybrid membrane microreactors for gas–liquid–solid (G–L–S) reactions. The presented reactors consist of porous stainless steel tubes onto which carbon nanofibers (CNFs) are grown as catalyst support, all encapsulated by a gas permeable coating. Such reactors benefit from a controlled G–L–S interface of a membrane reactor and high surface area of carbon nanofibers as catalyst support. Preparation steps such as porous stainless steel hollow fiber fabrication, CNF growth on the stainless steel surface, palladium catalyst immobilization and an outer gas permeable polymeric coating steps are presented. The fabricated microreactors have high surface area, mechanical strength and catalytic activity for nitrite reduction in water. Results proved high nitrite reduction performance of these reactors, even without the presence of palladium (Pd) or additional hydrogen (H2) supply. Our results suggest intrinsic reductant properties and catalytic activity of the reactors, which make them very suitable for hydrogenation reactions.