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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Javed, H.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2022Printability of carboxymethyl cellulose/glass-containing inks for robocasting deposition in reversible solid oxide cell applicationscitations
- 2021Mn-Co spinel coatings on Crofer 22 APU by electrophoretic deposition: Up scaling, performance in SOFC stack at 850 °C and compositional modificationscitations
- 2020Glass-ceramic sealants for SOEC: Thermal characterization and electrical resistivity in dual atmospherecitations
- 2019In-situ Cu-doped MnCo-spinel coatings for solid oxide cell interconnects processed by electrophoretic depositioncitations
- 2018Co-deposition of CuO and Mn 1.5 Co 1.5 O 4 powders on Crofer22APU by electrophoretic method: Structural, compositional modifications and corrosion propertiescitations
- 2018Co-deposition of CuO and Mn1.5Co1.5O4 powders on Crofer22APU by electrophoretic method: Structural, compositional modifications and corrosion propertiescitations
- 2016Mechanical characterization of metallic thin films by bulge and scratch testingcitations
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article
Co-deposition of CuO and Mn1.5Co1.5O4 powders on Crofer22APU by electrophoretic method: Structural, compositional modifications and corrosion properties
Abstract
Co-deposition of CuO and Mn<sub>1.5</sub>Co<sub>1.5</sub>O<sub>4</sub> by single step electrophoretic deposition is used to produce ∼15 µm coatings on Crofer22APU steel, which finds use as interconnect for high temperature solid oxide cells. Sintering of the green coatings in reducing and then oxidizing conditions led to formation of a mixed (Cu,Mn,Co)<sub>3</sub>O<sub>4</sub> spinel. By the incorporation of Cu, the density of the coatings improved. Scanning and transmission electron microscopy observations, supplemented with energy dispersive spectroscopy, confirmed dissolution of Cu in the spinel phase. For the un-doped Mn<sub>1.5</sub>Co<sub>1.5</sub>O<sub>4</sub> both the tetragonal and cubic phases are detected at room temperature by X-ray diffractometry, whereas the addition of Cu seems to stabilize the cubic phase. Initial (∼1000 h) high temperature corrosion evaluation at 800 °C in air showed promising properties of the mixed spinel coating.