| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Gressier, Marie
Université Toulouse III - Paul Sabatier
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2022Fabrication of a pH microsensor for local pH measurement during chromium electrodeposition from a trivalent chromium-based electrolytecitations
- 2022Fabrication of a pH microsensor for local pH measurement during chromium electrodeposition from a trivalent chromium-based electrolytecitations
- 2021Influence of Hybrid Sol-Gel Crosslinker on Self-Healing Properties for Multifunctional Coatingscitations
- 2020Near-Infrared Luminescence from Visible-Light-Sensitized Ruthenium(II)‑Neodymium(III) Heterobimetallic Bridged Complexes Containing Alkoxy(silyl) Functional Groupscitations
- 2018Innovative Formulation Combining Al, Zr and Si Precursors to Obtain Anticorrosion Hybrid Sol-Gel Coatingcitations
- 2016New architectured hybrid sol-gel coatings for wear and corrosion protection of low-carbon steelcitations
- 2016Bifunctional magnetic luminescent particles based on iron oxide nanoparticles grafted with a europium silylated bypiridine tris(β-diketonate) complexcitations
- 2016Luminescent multifunctional hybrids obtained by grafting of ruthenium complexes on mesoporous silicacitations
- 2013Protection against corrosion of magnesium alloys with both conversion layer and sol–gel coatingcitations
- 2012Improvement of barrier properties of a hybrid sol-gel coating by incorporation of synthetic talc-like phyllosilicates for corrosion protection of a carbon steelcitations
- 2009High rate capability pure Sn-based nano-architectured electrode assembly for rechargeable lithium batteriescitations
- 2009High rate capability pure Sn-based nano-architectured electrode assembly for rechargeable lithium batteriescitations
- 2007Silica-Based Nanohybrids Containing Dipyridine, Urethan, or Urea Derivativescitations
Places of action
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article
Luminescent multifunctional hybrids obtained by grafting of ruthenium complexes on mesoporous silica
Abstract
This work evaluates the luminescent properties of new hybrids obtained by covalent grafting of ruthenium complexes on mesoporous silica particles. Spray pyrolysis afforded the mesoporous silica particles in one step; two different types of structure-directing agents were employed. Scanning and transmission electron microscopy (SEM and TEM, respectively) analyses confirmed that the particles had spherical morphology and ordered hexagonal mesoporosity (2 and 5nm), which justified the high surface area up to 1420m2g-1 measured by Brunauer-Emmett-Teller (BET) surface area analysis. Covalent grafting of silylated ruthenium(II) complexes [Ru(bpy)21]Cl2 and [Ru(bpy)22]Cl2 on the mesoporous particles gave monolayered hybrids, characterized by fourier transform infrared spectroscopy (FTIR), TEM, and photoluminescence. Results highlighted the formation of new luminescent platforms containing an estimated 0.11mmol of ruthenium(II) complex per gram of silica, which corresponded to 0.09 ruthenium(II) complex nm−2 of silica.