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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Saviot, Lucien
Laboratoire Interdisciplinaire Carnot de Bourgogne
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Sensitivity of Localized Surface Plasmon Resonance and Acoustic Vibrations to Edge Rounding in Silver Nanocubescitations
- 2023Visible-light photocatalytic degradation of dyes by TiO2 -Au inverse opal films synthesized by Atomic Layer Depositioncitations
- 2022Mechanosynthesis of carbonate and lithium co-substituted hydroxyfluorapatitecitations
- 2022Mechanosynthesis of carbonate and lithium co-substituted hydroxyfluorapatitecitations
- 2019Iron oxide-based nanostructured ceramics with tailored magnetic and mechanical properties: Development of mechanically robust, bulk superparamagnetic materials
- 2019Iron oxide-based nanostructured ceramics with tailored magnetic and mechanical properties: development of mechanically robust, bulk superparamagnetic materialscitations
- 2017Direct Writing on Copper Ion Doped Silica Films by Electrogeneration of Metallic Microstructurescitations
- 2013Poisson ratio and excess low-frequency vibrational states in glassescitations
- 2013THz nanocrystal acoustic vibrations from ZrO2 3D supercrystalscitations
- 2012Growth of glass-embedded Cu nanoparticles: A low-frequency Raman scattering studycitations
- 2011Dielectric properties and Raman spectroscopy in Ca-substituted Na0.5Bi0.5TiO3 ferroelectric ceramicscitations
- 2008Surface enhanced Raman scattering of silver sensitized cobalt nanoparticles in metal–dielectric nanocompositescitations
- 2008Surface enhanced Raman scattering of silver sensitized cobalt nanoparticles in metal–dielectric nanocompositescitations
- 2007Polarizability calculation of vibrating nanoparticles for intensity of low wavenumber Raman scatteringcitations
Places of action
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article
Mechanosynthesis of carbonate and lithium co-substituted hydroxyfluorapatite
Abstract
The presence of fluoride, lithium and carbonate group within hydroxyapatite occurring naturally within the body provides the basis for investigating the sintering ability of co-substituted hydroxyfluorapatites nanopowders for use as biomaterials. Ca10-xLix(PO4)6-x(CO3)x(OH)F nanopowders, with x equal to 0, 0.5, 1, 1.5, 2 and 2.5 were prepared using mechanosynthesis and their extensive characterization was realized. Substitution causes contraction of the unit hexagonal cell along the a-axis and elongation along the c-axis, as well as a decrease in the degree of crystallinity of the powders, and an increase of the amounts of unreacted calcium and lithium carbonates. Crystallite sizes and strains, determined by the Halder & Wagner method, remain the same whatever x. Spectroscopic analyses show that B-type carbonated apatite is formed. Annealing at 500°C improves the crystallinity of the apatite phase with low percentages of calcite and lithium phosphate as secondary phases (x<=2). Transmission electron microscopy observations show that untreated and calcined powders consist mainly of spherical nanoparticles. As-mechanosynthesized Ca9Li(PO4)5(CO3)(OH)F powder, sintered by Spark Plasma 2 Sintering, densifies in the temperature range of 580 to 650 °C. The crystallite size remains the same than that of the untreated-powder (about 15 nm).