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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Slater, Peter
University of Birmingham
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (45/45 displayed)
- 2024Direct recycling of EV production scrap NMC532 cathode materialscitations
- 2024Phase-selective recovery and regeneration of end-of-life electric vehicle blended cathodes via selective leaching and direct recyclingcitations
- 2023The effects of sintering temperature and current contacting layer on the performance of lanthanum nickelate electrodes in Solid Oxide Fuel Cellscitations
- 2023Phase-selective recovery and regeneration of end-of-life electric vehicle blended cathodes via selective leaching and direct recyclingcitations
- 2023Assessing boron doped Ba2In1.8Si0.2O5.1 as a potential electrolyte for use in ceramic electrolyte fuel cellscitations
- 2023Rapid sintering of Li6.5La3Zr1Nb0.5Ce0.25Ti0.25O12 for high density lithium garnet electrolytes with current induced in-situ interfacial resistance reduction.citations
- 2022Roadmap on Li-ion battery manufacturing researchcitations
- 2022Rheology and structure of lithium‐ion battery electrode slurriescitations
- 2021Electrochemical reduction and oxidation of Ruddlesden–Popper-type La2NiO3F2 within fluoride-ion batteriescitations
- 2021Evaluation of Ga0.2Li6.4Nd3Zr2O12 garnetscitations
- 2021Structural, magnetic and catalytic properties of a new vacancy ordered perovskite type barium cobaltate BaCoO2.67citations
- 2020Synthesis and characterisation of Sr4Fe3-xCrxO10-δ citations
- 2020Carbon dioxide and water incorporation mechanisms in SrFeO3−δ phasescitations
- 2020Suitability of strontium and cobalt-free perovskite cathodes with La9.67Si5AlO26 apatite electrolyte for intermediate temperature solid oxide fuel cellscitations
- 2020Topochemical fluorination of n = 2 Ruddlesden–Popper type Sr3Ti2O7 to Sr3Ti2O5F4 and its reductive defluorinationcitations
- 2019BaCoO2+δcitations
- 2018Topochemical Fluorination of La2NiO4+d:citations
- 2016Exploring the mixed transport properties of sulfur (VI)-doped Ba2In2O5 for intermediate-temperature electrochemical applicationscitations
- 2016Modification of magnetic and electronic properties, in particular superconductivity, by low temperature insertion of fluorine into oxidescitations
- 2016Synthesis, structural characterisation and proton conduction of two new hydrated phases of barium ferrite BaFeO2.5−x(OH)2xcitations
- 2015Crystal chemical analysis of Nd9.33Si6O26 and Nd8Sr2Si6O26 apatite electrolytes using aberration-corrected scanning transmission electron microscopy and impedance spectroscopycitations
- 2015Laser machining of LaNi0.6M0.4O3−δ (M: Co, Fe) dip-coated on a Fe-22Cr mesh material to obtain a new contact coating for SOFCcitations
- 2015Synthesis and characterization of novel Ge doped Sr1−yCayFeO3−δ SOFC cathode materialscitations
- 2014LaNi0.6Co0 4O3−δ dip-coated on Fe–Cr mesh as a composite cathode contact material on intermediate solid oxide fuel cellscitations
- 2014Crystallographic and magnetic structure of the perovskite-type compound BaFeO2.5 : unrivaled complexity in oxygen vacancy orderingcitations
- 2014High valence transition metal doped strontium ferrites for electrode materials in symmetrical SOFCscitations
- 2014Hydrothermal synthesis, structure investigation, and oxide ion conductivity of mixed Si/Ge-based apatite-type phasescitations
- 2013Investigation into the effect of Si doping on the performance of SrFeO3−δ SOFC electrode materialscitations
- 2013Investigation into the effect of Si doping on the performance of Sr1−yCayMnO3−δ SOFC cathode materialscitations
- 2012Low temperature fluorination of Sr3Fe2O7-x with polyvinylidine fluoride: An X-ray powder diffraction and Mossbauer spectroscopy studycitations
- 2012Synthesis and characterisation of oxyanion-doped manganites for potential application as SOFC cathodescitations
- 2011Structure and magnetic properties of the cubic oxide fluoride BaFeO2Fcitations
- 2010Synthesis and characterisation of the SrxBa1-xFeO3-y-system and the fluorinated phases SrxBa1-xFeO2Fcitations
- 2010Crystal chemistry and optimization of conductivity in 2A, 2M and 2H alkaline earth lanthanum germanate oxyapatite electrolyte polymorphscitations
- 2009Fluorination of perovskite-related phases of composition SrFe1-xSnxO3-deltacitations
- 2009Solid-State Materials for Clean Energy: Insights from Atomic-Scale Modeling
- 2008A high temperature powder neutron diffraction structural study of the apatite-type oxide ion conductor, La9.67Si6O26.5citations
- 2008Synthesis and structural investigation of a new oxide fluoride of composition Ba2SnO2.5F3·xH2O (x≈0.5)citations
- 2008Magnetic order in perovskite-related SrFeO2Fcitations
- 2007Insight into doping effects in apatite silicate ionic conductorscitations
- 2007Investigation of the structural changes on Zn doping in the apatite-type oxide ion conductor La9.33Si6O26citations
- 2007Identification of the Li sites in the Li ion conductor, Li6SrLa2Nb2O12, through neutron powder diffraction studiescitations
- 2007Structural studies of the proton conducting perovskite 'La0.6Ba0.4ScO2.8'citations
- 2007Cooperative mechanisms of fast-ion conduction in gallium-based oxides with tetrahedral moietiescitations
- 2006Neutron diffraction and atomistic simulation studies of Mg doped apatite-type oxide ion conductorscitations
Places of action
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article
Synthesis and characterization of novel Ge doped Sr1−yCayFeO3−δ SOFC cathode materials
Abstract
In this paper we report the successful incorporation of germanium into Sr1−yCayFeO3−δ perovskite materials for potential applications as electrode materials for solid oxide fuel cells. It was observed that Ge doping leads to a change from a tetragonal cell (with partial ordering of oxygen vacancies) to a cubic one (with the oxygen vacancies disordered). Annealing experiments in 5%H2/95%N2 (up to 800 °C) also showed the stabilization of the cubic form in reducing conditions for the 15 mol% Ge-doped SrFeO3−δ sample, in contrast to the undoped systems which showed a transition to an oxygen vacancy ordered brownmillerite-type phase. In order to examine the potential of these systems as SOFC cathodes, composite electrodes comprising 50% Ce0.9Gd0.1O1.95 and 50% Sr1−yCay(Fe/Ge)O3−δ on dense Ce0.9Gd0.1O1.95 pellets were examined in air. The results showed an improvement in the area specific resistances (ASR) values for the Ge-doped samples with respect to the undoped ones, with the best performance for the Ge doped SrFeO3−δ system (0.24 and 0.06 Ω cm2 at 700 and 800 °C, respectively, for SrFe0.85Ge0.15O3−δ). Thus, the results show that germanium can be incorporated into Sr1−yCayFeO3−δ-based materials leading to materials with potential for use as cathode materials in solid oxide fuel cells (SOFC).