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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Schlögl, Sandra
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (33/33 displayed)
- 2024Cationic UV-curing of bio-based epoxidized castor oil vitrimers with electrically conductive propertiescitations
- 2024Dual-vat photopolymerization 3D printing of vitrimerscitations
- 2024Reprocessable carbon fiber vitrimer composites: Reclamation and reformatting of carbon fibers for second generation composite materials
- 2024Rapid tooling for rubber extrusion molding by digital light processing 3D printing with dual curable vitrimerscitations
- 2024MetamaterialFindercitations
- 2024Redox cationic frontal polymerization: a rapid curing approach for carbon fiber-reinforced composites with high fiber contentcitations
- 2024Vitrimer Transition Phenomena from the Perspective of Thermal Volume Expansion and Shape (In)stabilitycitations
- 2024Design of Reversible Adhesives by Using a Triple Function of Ionic Liquidscitations
- 2023Accelerated Thermo-Catalytic Degradation of Perfluoropolyether (PFPE) Lubricants for Space Applicationscitations
- 2023Ti$_{40}$Zr$_{10}$Cu$_{36}$Pd$_{14}$ bulk metallic glass as oral implant materialcitations
- 2023Thermally Latent Bases in Dynamic Covalent Polymer Networks and their Emerging Applicationscitations
- 2023On‐Demand Activation of Transesterification by Chemical Amplification in Dynamic Thiol‐Ene Photopolymerscitations
- 2023Sustainable Bio-Based UV-Cured Epoxy Vitrimer from Castor Oilcitations
- 2023Redox cationic frontal polymerizationcitations
- 2023Ti40Zr10Cu36Pd14 bulk metallic glass as oral implant materialcitations
- 2022Influence of morphology and chemical surface composition on electrical conductivity of SiC microspherescitations
- 2022Asymmetric chiral and antichiral mechanical metamaterials with tunable Poisson's ratiocitations
- 2021High resolution additive manufacturing with acrylate based vitrimers using organic phosphates as transesterification catalystcitations
- 2021Structural Model for the Estimation of the Equivalent Permittivity of Nanodielectrics Based on Polyethylene and Epoxy Resins
- 2021Introduction of Photolatent Bases for Locally Controlling Dynamic Exchange Reactions in Thermo-Activated Vitrimerscitations
- 2021Investigating the influence of surface hardness and energy on the perceived stickiness of polymer coatings.
- 2021Role of Organic Phosphates and Phosphonates in Catalyzing Dynamic Exchange Reactions in Thiol-Click Vitrimerscitations
- 2021Functional mechanical metamaterial with independently tunable stiffness in the three spatial directionscitations
- 2020Tailored Interfaces in Fiber-Reinforced Elastomerscitations
- 2020Epoxy-anhydride vitrimers from aminoglycidyl resins with high glass transition temperature and efficient stress relaxationcitations
- 2020Design and characterisation of vitrimer-like elastomeric composites from HXNBR rubbercitations
- 2020Exploiting the Carbon and Oxa Michael Addition Reaction for the Synthesis of Yne Monomerscitations
- 2020Tribological characteristics of medical gloves in contact with human skin and skin equivalentscitations
- 2019Bonded aerospace repairs under tensile loading: Wet chemical surface treatment and selected environmental conditionscitations
- 2018Tailoring the interfaces in glass fiber-reinforced photopolymer compositescitations
- 2017Synthesis and evaluation of new radical photoinitiators bearing trialkoxysilyl groups for surface immobilizationcitations
- 2016Thiol-Ene versus Binary Thiol–Acrylate Chemistrycitations
- 2016Flexible epoxy based composites with enhanced delamination resistance
Places of action
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article
Ti40Zr10Cu36Pd14 bulk metallic glass as oral implant material
Abstract
The application of highly biocompatible advanced materials leads to fewer complications and more successful medical treatments. This study proposes Ti40Zr10Cu36Pd14 bulk metallic glass (BMG) as an oral implant material and provides insights into its possible processing routes, where high-temperature compression molding via an optimized process is adopted to both evaluate the thermoplastic net-shaping kinetics and tune the specific properties of the alloy. We present processed BMGs and BMG composites of the same composition with improved thermomechanical stability, from which high strength retention at temperatures, compared to the cast glass, by above 100 K higher is registered via dynamic mechanical analysis. ∼100 nm thin surface layers comprised of Ti, Cu, and Zr oxides form at the surface of the alloys, as identified by high-resolution transmission microscopy. Also, ∼4 orders of magnitude lower passivation current density along with ∼2 orders of magnitude lower corrosion current density of the processed glass compared to the values of the as-cast state confirms an extremely high stability in a 0.9 wt% saline environment which can be linked to surface hydrophobicity. Cytocompatibility analysis conducted by seeding human gingival fibroblast cells directly onto the thermoplastically formed Ti40Zr10Cu36Pd14 BMG reveals no adverse effect on cytocompatibility. On the other hand, the formation of a nanoscale oxide layer on the thermoplastically formed samples leads to significantly higher cell attachments on the surface.