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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sajdl, Petr
University of Chemistry and Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Measurement system for in-situ estimation of instantaneous corrosion rate in supercritical watercitations
- 2023Beyond the Platinum Era─Scalable Preparation and Electrochemical Activation of TaS2 Flakescitations
- 2023Exploring morphological diversity of Q-carbon structures through laser energy density variationcitations
- 2022KrF Laser and Plasma Exposure of PDMS–Carbon Composite and Its Antibacterial Propertiescitations
- 2022Carbon Transformation Induced by High Energy Excimer Treatmentcitations
- 2022Surface modifications of a silicalite film designed for coating orthopaedic implantscitations
- 2022Plasma treatment of PTFE at elevated temperature: The effect of surface properties on its biological performancecitations
- 2021The effect of material and process parameters on the surface energy of polycaprolactone fibre layerscitations
- 2020Studium oxidových vrstev na slitinách zirkonia Ramanovou spektroskopií
- 2020Zr alloy protection against high-temperature oxidation: Coating by a double-layered structure with active and passive functional propertiescitations
- 2020Raman study of oxide layers on zirconium alloys using 18O tracerscitations
- 2020Cellulose acetate honeycomb-like pattern created by improved phase separationcitations
- 2017Nanocrystalline diamond protects Zr cladding surface against oxygen and hydrogen uptake : Nuclear fuel durability enhancementcitations
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article
Surface modifications of a silicalite film designed for coating orthopaedic implants
Abstract
The effect of various surface modifications of silicalite-1 film grown on a Ti6Al4V alloy on biocompatibility and cell differentiation has been addressed. The as-synthesized silicalite film was first modified by alkaline etching and by subsequent treatments in oxygen radiofrequency (O2 RF) plasma, by calcination at 500 °C, and by processing the calcinated samples in the O2 RF plasma. The chemical composition, crystallinity, topography and wettability of samples were characterized using angle-resolved X-ray photoelectron spectroscopy, X-ray diffraction, scanning electron microscopy, and sessile water drop contact angle measurements. We have discovered the presence of a non-zeolitic defective SiOx phase (NZP) with coordinated hydrocarbon chains. The NZP can be removed by the exposition to the O2 RF plasma. The metabolic activity tests done on human osteoblast line Saos-2 revealed that the NZP can influence cell proliferation; however, all studied modifications of silicalite film can be considered biocompatible. The osteogenic differentiation was studied on human mesenchymal stem cells under static conditions and under dynamic (pulsatile and shear) stress. The results obtained by the real-time qPCR and immunofluorescence microscopy suggest that etched, plasma-treated and calcinated + plasma-treated samples are the most promising for osteogenic cell differentiation. © 2022 The Authors