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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Fornell, Jordina
Universitat Autònoma de Barcelona
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023Surface Modified β-Ti-18Mo-6Nb-5Ta (wt%) Alloy for Bone Implant Applications:citations
- 2023Surface Modified β-Ti-18Mo-6Nb-5Ta (wt%) Alloy for Bone Implant Applications: Composite Characterization and Cytocompatibility Assessment
- 2018Large magnetoelectric effects in electrodeposited nanoporous microdisks driven by effective surface charging and magneto-ionicscitations
- 2018Mapping of magnetic and mechanical properties of Fe-W alloys electrodeposited from Fe(III)-based glycolate-citrate bathcitations
- 2017Mechanical properties, corrosion performance and cell viability studies on newly developed porous Fe-Mn-Si-Pd alloyscitations
- 2016Single step electrosynthesis of NiMnGa alloyscitations
- 2016Novel Fe-Mn-Si-Pd alloys: Insights into mechanical, magnetic, corrosion resistance and biocompatibility performancescitations
- 2015Nanostructured Ti-Zr-Pd-Si-(Nb) bulk metallic composites: Novel biocompatible materials with superior mechanical strength and elastic recoverycitations
- 2013Novel Ti-Zr-Hf-Fe nanostructured alloy for biomedical applicationscitations
- 2012Improved mechanical performance and delayed corrosion phenomena in biodegradable Mg-Zn-Ca alloys through Pd-alloyingcitations
Places of action
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article
Mapping of magnetic and mechanical properties of Fe-W alloys electrodeposited from Fe(III)-based glycolate-citrate bath
Abstract
Electrodeposition of Fe-W coatings has been carried out from an environmentally friendly Fe(III)-based glycolate-citrate bath. Samples with tungsten content from 6 to 25 at.% were electrodeposited in a controlled way by changing electrodeposition parameters: current density, pH, and temperature. X-ray diffraction analysis showed that the structure of Fe-W coatings transforms from nanocrystalline to amorphous-like as the W content increases and the crystallite size reduces below 10 nm. However, the peculiarities of the structural transitions are linked not only with the W content. Deposition temperature plays a crucial role, due to the different activation energy of crystallization. Following the direct Hall–Petch relation, a maximum hardness of ~ 10 GPa was found for the alloy with the highest W content, making it comparable to that of electrolytic chromium. The Fe2W intermetallic compound forms at higher W concentration as proven by Mössbauer spectroscopy, and contributes to the increased hardness of these alloys. The alloys retain a soft magnetic character within a wide compositional range, although increasing the W content leads to a reduction of the saturation magnetization. Fe-12 at.% W coatings show an optimum combination of mechanical and magnetic properties, thus making these newly developed coatings appealing environmentally-friendly alternative materials for multi-scale technologies.