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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bendeif, El-Eulmi
Soleil Synchrotron
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Role and Effect of Meso-Structuring Surfactants on Properties and Formation Mechanism of Microfluidic-Enabled Mesoporous Silica Microspherescitations
- 2023Crystal Structure, Hirhfeld Surface Analysis and IR Analysis of 2-Amino-1,9-Dihydro-6H-Purin-6-One-Selenate-Watercitations
- 2023Synthesis, catalytic activity, magnetic study and anticorrosive activity of mild steel in HCl 1 M medium of (H3dien)[Cu(NO3)(C2O4)2].2H2O. A redetermination at 100 Kcitations
- 2021Synthesis, structural elucidation, spectroscopic, Hirshfeld surface analysis and theoretical simulation of a new adeninium orthoperiodate (1−) bis(hydrate) organic–inorganic hybrid crystalscitations
- 2018Conducting Anilate-Based Mixed-Valence Fe(II)Fe(III) Coordination Polymer: Small-Polaron Hopping Model for Oxalate-Type Fe(II)Fe(III) 2D Networkscitations
- 2018Conducting Anilate-Based Mixed-Valence Fe(II)Fe(III) Coordination Polymer: Small-Polaron Hopping Model for Oxalate-Type Fe(II)Fe(III) 2D Networks
- 2018Broadband Emission in a New Two-Dimensional Cd-Based Hybrid Perovskitecitations
- 2017Control of the white-light emission in the mixed two-dimensional hybrid perovskites (C6H11NH3)2[PbBr4−xIx]citations
- 2017In-house time-resolved photocrystallography on the millisecond timescale using a gated X-ray hybrid pixel area detectorcitations
- 2015Structure determination of molecular nanocomposites by combining pair distribution function analysis and solid-state NMRcitations
- 2015Optical Investigation of Broadband White-Light Emission in Self-Assembled Organic-Inorganic Perovskite (C6H11NH3)(2)PbBr4citations
- 2013Room temperature bistability with wide thermal hysteresis in a spin crossover silica nanocompositecitations
- 2013Room temperature bistability with wide thermal hysteresis in a spin crossover silica nanocompositecitations
- 2013Structural reinvestigation of the photoluminescent complex [NdCl2(H2O)(6)]Clcitations
Places of action
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article
Synthesis, catalytic activity, magnetic study and anticorrosive activity of mild steel in HCl 1 M medium of (H3dien)[Cu(NO3)(C2O4)2].2H2O. A redetermination at 100 K
Abstract
Diethylenetriammonium nitrato-bis(oxalato)cuprate (II) dihydrate (H 3 dien)[Cu(NO 3)(C 2 O 4) 2 ].2H 2 O (1) was synthesized by wet chemistry method. It was assessed for thermal stability (TG-DTA), single crystal X-ray diffraction, Fourier Transform Infrared spectroscopy (FTIR) and magnetic measurements. 1 crystallizes in the monoclinic system (P2 1 /c), with the parameters: a= 10.1054(5) Å, b= 11.0825(5) Å, c= 14.8238(7) Å, β= 103.516(5)°, V= 1614.2 (1) Å 3 and Z= 4. The complex anions are distributed into layers, whilst the self-assembly of the inorganic-organic entities is assured by an intricate hydrogen network. At 413 K, the thermal behavior predominantly consists of the removal of water molecules, while its infrared spectrum displays distinct bands of oxalate, nitrate and diethylenetriamine groups. The catalytic test indicated that complex 1 exhibits a good catalytic activity in nitrophenol isomers (NP) reduction to aminophenols (AP). Moreover, 1 showed a high photocatalytic degradation efficiency 90% at 90 min toward the methylene blue (MB) dye under the UV irradiation. Due to the presence of the heteroatoms in its structure, the examined hybrid material's corrosion-inhibiting action in acidic conditions was more pronounced.