| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Andersen, Emil
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2023The Effect of Physical Aging on the Viscoelastoplastic Response of Glycol Modified Poly(ethylene terephthalate)citations
- 2023Accelerated physical aging of four PET copolyesterscitations
- 2023Accelerated physical aging of four PET copolyesters:Enthalpy relaxation and yield behaviourcitations
- 2021Real-time ageing of polyesters with varying diolscitations
- 2021Attention Affordances: Applying Attention Theory to the Design of Complex Visual Interfacescitations
- 2020Accelerating effect of pigments on poly(acrylonitrile butadiene styrene) degradationcitations
- 2019Accelerated physical ageing of poly(1,4-cyclohexylenedimethylene-co-2,2,4,4-tetramethyl-1,3-cyclobutanediol terephthalate)citations
- 2018Straight forward approach for obtaining relaxation-recovery data
Places of action
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article
Real-time ageing of polyesters with varying diols
Abstract
<p>Polyesters are a widely used class of polymer due to their excellent processing, mechanical and recycling properties. However, polyesters are usually not used for durable goods. Thus, further understanding of underlying chemical and physical degradation mechanisms and their changes when changing the chemical composition of the polymer is required. This work presents four polyesters with varying diols (recycled poly (ethylene terephthalate) (PET-R), poly (butylene terephthalate) (PBT), poly (ethylene glycol-co-2,2,4,4-tetramethyl-1,3-cyclobutanediol terephthalate) (PETG) and poly (1,4-cyclohexylenedimethylene-co-2,2,4,4-tetramethyl-1,3-cyclobutanediol terephthalate) PCTT) submitted to a real-time exposure in Southern France for almost two years (16056 h). This environment demonstrated an average temperature of 20.6 °C, relative humidity of 61.4%RH and UV exposure (300–400 nm) of 0.95 MJ/m<sup>2</sup>. Differential scanning calorimetry showed significant physical ageing of the PET-R. Attenuated total reflectance Fourier transform infrared spectroscopy presented the loss and shift of the ester bond with an increase in hydroxyl species, as a result of significant chain scission of the polyesters. Degradation dominated the mechanical toughness response, resulting in all polyesters to become increasingly brittle with ageing. While the reference (t = 0 h) charpy v-notch toughness was 3.2, 2.6, 5.0 and 104 for PET-R, PBT, PETG and PCTT, respectively, they all decreased to below 1.5 kJ/m<sup>2</sup> after 2928 h of ageing. Similar behaviour was observed for charpy weld line toughness with reference between 93 and 290 kJ/m<sup>2</sup> and decreased to 1.8–2.2 kJ/m<sup>2</sup>. PET-R demonstrated the highest tensile elongation after ageing, but despite this PCTT was the last polyester to decrease significantly below the reference, presenting that PCTT was significantly more resistant towards ageing induced embrittlement.</p>