| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Kumar, Abhinav
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Optimization of surface roughness in milling of EN 24 steel with WC-Coated inserts using response surface methodology: analysis using surface integrity microstructural characterizationscitations
- 2024Biosurfactants in biocorrosion and corrosion mitigation of metals: An overviewcitations
- 2023The Microstructure and Properties of Ni-Si-La2O3 Coatings Deposited on 304 Stainless Steel by Microwave Claddingcitations
- 2023Prediction and simulation of mechanical properties of borophene-reinforced epoxy nanocomposites using molecular dynamics and FEAcitations
- 2023Effect of Pulsation in Microstructure and Mechanical Properties of Titanium Alloy-Annealed Welded Joints at Different Temperaturescitations
- 2022Diaminopyridine Hg(II)-based 1D supramolecular polymercitations
- 2022Ferrocene Appended Asymmetric Sensitizers with Azine Spacers with phenolic/nitro anchors for Dye-Sensitized Solar Cellscitations
- 2020A new 1D coordination polymer of triphenyl lead hydrosulfide: Synthesis and insights into crystal architecture and Hirshfeld surface analysescitations
- 2016Transition metal ferrocenyl dithiocarbamates functionalized dye-sensitized solar cells with hydroxy as an anchoring groupcitations
Places of action
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article
Diaminopyridine Hg(II)-based 1D supramolecular polymer
Abstract
<p>A new Hg(II)-based one dimensional supramolecular polymer with a molecular formula of [(C<sub>5</sub>H<sub>3</sub>N(NH<sub>2</sub>)<sub>2</sub>Cl<sub>2</sub>Hg)]<sub>n</sub> (1) has been synthesized and characterized using microanalysis, FTIR, UV–Vis., multinuclear NMR and single crystal X-ray diffraction. The X-ray diffraction reveals initially a three coordinated geometry around the Hg(II) centre, coordinated covalently with two non-coplanar chlorine atoms and one nitrogen atom of the 2,6-diamino pyridine ring. Furthermore, two more chlorine centers form a bridge between two Hg centers through the Hg⋯Cl spodium bond interaction to furnish a pseudo trigonal bipyramidal geometry (τ<sub>5</sub> = 0.957) in a supramolecular polymer. The solid state architecture of the polymer is stabilised by different weak interactions and it also exhibit unconventional Hg⋯Cl spodium and Hg⋯H–N interactions. The nature of these interactions have been investigated using Hirshfeld surface analyses, density functional theory and quantum theory of atoms in molecules (QTAIM) studies. The emission studies for the compound in both solution and solid phase have also been executed.</p>