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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bos, Jan-Willem Gezienes
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Alloying and doping control in the layered metal phosphide thermoelectric CaCuPcitations
- 2023Thermoelectric properties and Kondo transition in the pseudo-gap metals TiNiSi and TiNiGe
- 2023Alloying and doping control in the layered metal phosphide thermoelectric CaCuPcitations
- 2023Thermoelectric properties of the aliovalent half-Heusler alloy Zn0.5Ti0.5NiSb with intrinsic low thermal conductivitycitations
- 2019Suppression of thermal conductivity without impeding electron mobility in n-type XNiSn half-Heusler thermoelectricscitations
- 2019Phase stability and thermoelectric properties of TiCoSb-TiM2Sn (M = Ni, Fe) Heusler compositescitations
- 2018Grain-by-grain compositional variations and interstitial metals - a new route towards achieving high performance in Half-Heusler thermoelectricscitations
- 2018Substitution versus full-Heusler segregation in TiCoSbcitations
- 2016Thermoelectric properties and high-temperature stability of the Ti1-xVxCoSb1-xSnx half-Heusler alloyscitations
- 2015Efficient thermoelectric performance in silicon nano-films by vacancy-engineeringcitations
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article
Phase stability and thermoelectric properties of TiCoSb-TiM2Sn (M = Ni, Fe) Heusler composites
Abstract
Heusler composites have attracted significant attention as a new route towards improving the thermoelectric figure of merit (ZT) through reduction of the lattice thermal conductivity and carrier filtering effects. This work extends this field by investigating TiCoSb-TiM2Sn (M = Ni, Fe) composites. All end-members are stable phases but no clean segregation into half- and full-Heusler phases was observed. Instead, for M = Ni, partial substitution on the Co sublattice and n-type doping occurs, combined with the formation of Ni3Sn2 and full-Heusler phases. For M = Fe, substitution on the Co site occurs, leading to p-type conduction. Rietveld analysis of neutron powder diffraction data reveals no evidence for the presence of metals on the vacant tetrahedral site, signalling the absence of embedded Heusler inclusions. The thermoelectric properties of both series vary systematically with composition. For both n-type (M = Ni) and p-type (M = Fe) series, the highest measured power factors S2/ρ ∼ 0.8 mW m−1 K−2 leading to ZT ∼ 0.12 at 713 K. This work extends knowledge regarding the phase stability and thermoelectric properties of TiCoSb-based Heusler composites.