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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mclaughlin, Abbie
University of Aberdeen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2022Variable Temperature Neutron Diffraction Study of the Oxide Ion Conductor Ba3VWO8.5citations
- 2021A pressure induced reversal to the 9R perovskite in Ba3MoNbO8.5citations
- 2018Physicochemical Toolscitations
- 2017An investigation of the electronic, structural and magnetic properties of the ruddlesden-popper phase Sr3RuCoO7citations
- 2016An investigation of the optical properties and water splitting potential of the coloured metallic perovskites Sr1-xBaxMoO3citations
- 2016A Variable Temperature Synchrotron X-ray Diffraction Study of Colossal Magnetoresistant NdMnAsO0.95F0.05citations
- 2016The Structure and Optical Properties of Sr1-xCaxMoO3citations
- 2014Structural and magnetic characterisation of the novel spin frustrated double perovskite Sr2ScMoO6citations
- 2010Valence bond glass on an fcc lattice in the double perovskite Ba2YMoO6citations
- 2010Persistence of the valence bond glass state in the double perovskites Ba2-xSrxYMoO6citations
- 2006Magnetic and structural studies of the double perovskites Ba2REMoO6citations
- 2006Defect structure of ferromagnetic superconducting RuSr2GdCu2O8citations
- 2003Magnetotransport properties of doped RuSr2GdCu2O8citations
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article
An investigation of the optical properties and water splitting potential of the coloured metallic perovskites Sr1-xBaxMoO3
Abstract
<p>The solid solution Sr1-xBaxMoO3 (x=0.00, 0.025, 0.050, 0.075, 0.100 and 1.00) has been synthesised. Rietveld refinement of X-ray diffraction data shows that all materials crystallise with cubic (Pm-3m) symmetry and that a miscibility gap exists from x=0.1-1.0. The optical properties of the metallic perovskites Sr1-xBaxMoO3 have been investigated by a combination of UV-vis spectroscopy and density functional theory (DFT). Upon increasing x from 0 to 1 in Sr(1-)xBa(x)MoO(3) there is a reduction in the measured band gap from 2.20 eV to 2.07 eV. The measured band gap is attributed to the electronic transition from the Mo 4d t(2g) band to the e(g) band. The potential of SrMoO3 and BaMoO3 as water-splitting photocatalysts was explored but there was no evidence of hydrogen or oxygen evolution, even with the presence of a Pt co-catalyst. (C) 2015 Elsevier Inc. All rights reserved.</p>