| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Norby, Poul
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (34/34 displayed)
- 2023Thin film and bulk morphology of PI-PS-PMMA miktoarm star terpolymers with both weakly and strongly segregated arm pairs
- 2023Time and space resolved operando synchrotron X-ray and Neutron diffraction study of NMC811/Si–Gr 5 Ah pouch cellscitations
- 2019Electrochemical stability of (La,Sr)CoO3-δ in (La,Sr)CoO3-δ/(Ce, Gd)O2-δ heterostructurescitations
- 2019Improved cycling stability in high-capacity Li-rich vanadium containing disordered rock salt oxyfluoride cathodescitations
- 2019Hydrothermal Synthesis, Characterization, and Sintering Behavior of Core-Shell Particles: A Principle Study on Lanthanum Strontium Cobaltite Coated with Nanosized Gadolinium Doped Ceriacitations
- 2019Hydrothermal Synthesis, Characterization, and Sintering Behavior of Core-Shell Particles: A Principle Study on Lanthanum Strontium Cobaltite Coated with Nanosized Gadolinium Doped Ceriacitations
- 2018Intercalation of lithium into disordered graphite in a working batterycitations
- 2018Hydrothermal Synthesis, Characterization, and Sintering Behavior of Core-Shell Particles: A Principle Study on Lanthanum Strontium Cobaltite Coated with Nanosized Gadolinium Doped Ceriacitations
- 2017Investigation of a Spinel-forming Cu-Mn Foam as an Oxygen Electrode Contact Material in a Solid Oxide Cell Single Repeating Unitcitations
- 2016Electron microscopy investigations of changes in morphology and conductivity of LiFePO4/C electrodescitations
- 2016Comprehensive analysis of TEM methods for LiFePO 4 /FePO 4 phase mapping: spectroscopic techniques (EFTEM, STEM-EELS) and STEM diffraction techniques (ACOM-TEM)citations
- 2016In situ X-ray powder diffraction studies of the synthesis of graphene oxide and formation of reduced graphene oxidecitations
- 2016Comprehensive analysis of TEM methods for LiFePO4/FePO4 phase mapping: spectroscopic techniques (EFTEM, STEM-EELS) and STEM diffraction techniques (ACOM-TEM)citations
- 2016Electron microscopy investigations of changes in morphology and conductivity of LiFePO 4 /C electrodescitations
- 2016Nanocomposite YSZ-NiO Particles with Tailored Structure Synthesized in a Two-Stage Continuous Hydrothermal Flow Reactor
- 2015In Situ Studies of Fe4+ Stability in β-Li3Fe2(PO4)3 Cathodes for Li Ion Batteriescitations
- 2015Size of oxide vacancies in fluorite and perovskite structured oxidescitations
- 2015In Situ High Resolution Synchrotron X-Ray Powder Diffraction Studies of Lithium Batteries
- 2015Capillary based Li-air batteries for in situ synchrotron X-ray powder diffraction studiescitations
- 2014Ionic conductivity and the formation of cubic CaH 2 in the LiBH 4 -Ca(BH 4 ) 2 compositecitations
- 2014Degradation Studies on LiFePO 4 cathode
- 2014Ionic conductivity and the formation of cubic CaH2 in the LiBH4-Ca(BH4)2 compositecitations
- 2014Degradation Studies on LiFePO4 cathode
- 2014In Situ Synchrotron XRD on a Capillary Li-O2 Battery Cell
- 2014Temperature- and Pressure-Induced Changes in the Crystal Structure of Sr(NH3)8Cl2citations
- 2013Structure and Magnetic Properties of Cu 3 Ni 2 SbO 6 and Cu 3 Co 2 SbO 6 Delafossites with Honeycomb Latticescitations
- 2013Structure and Magnetic Properties of Cu3Ni2SbO6 and Cu3Co2SbO6 Delafossites with Honeycomb Latticescitations
- 2013Capillary-based micro-battery cell for in situ X-ray powder diffraction studies of working batteries: a study of the initial intercalation and deintercalation of lithium into graphitecitations
- 2012Subsolidus phase relations of the SrO–WO3–CuO system at 800 °C in aircitations
- 2012Subsolidus phase relations of the SrO–WO 3 –CuO system at 800 °C in aircitations
- 2010Structural and microstructural changes during anion exchange of CoAl layered double hydroxides: an in situ X-ray powder diffraction studycitations
- 2009A Structural Study of Stacking Disorder in the Decomposition Oxide of MgAl Layered Double Hydroxide: A DIFFaX plus Analysiscitations
- 2009Conductivity and water uptake of Sr-4(Sr2Nb2)O-11 center dot nH(2)O and Sr-4(Sr2Ta2)O-11 center dot nH(2)Ocitations
- 2009Temperature dependant X-ray diffraction study of PrSr3Co1.5Fe1.5O10-d; n=3 Ruddlesden-Popper phasecitations
Places of action
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article
Ionic conductivity and the formation of cubic CaH2 in the LiBH4-Ca(BH4)2 composite
Abstract
LiBH4–Ca(BH4)2 composites were prepared by ball milling. Their crystal structures and phase composition were investigated using synchrotron X-ray diffraction and Rietveld refinement, and their ionic conductivity was measured using impedance spectroscopy. The materials were found to form a physical mixture. The composites were composed of α-Ca(BH4)2, γ-Ca(BH4)2 and orthorhombic LiBH4, and the relative phase quantities of the Ca(BH4)2 polymorphs varied significantly with LiBH4 content. The formation of small amounts of orthorhombic CaH2 and cubic CaH2 in a CaF2-like structure was observed upon heat treatment. Concurrent formation of elemental boron may also occur. The ionic conductivity of the composites was measured using impedance spectroscopy, and was found to be lower than that of ball milled LiBH4. Electronic band structure calculations indicate that cubic CaH2 with hydrogen defects is electronically conducting. Its formation along with the possible precipitation of boron therefore has an effect on the measured conductivity of the LiBH4–Ca(BH4)2 composites and may increase the risk of an internal short-circuit in the cells.