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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wright, Adrian
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2011Biocompatibility of magnesium phosphate minerals and their stability under physiological conditionscitations
- 2011Structure and magnetic properties of the cubic oxide fluoride BaFeO2Fcitations
- 2009Influence of cooling rate on the structure and composition of NaxCoO2 (x similar to 0.65)citations
- 2009Fluorination of perovskite-related phases of composition SrFe1-xSnxO3-deltacitations
- 2006Crystal structure and magnetic properties of Ca₂MnAlO₅.₅, an n=3 brownmillerite phasecitations
- 2004Crystallographic and magnetic structures of Y₀.₈Sr₂.₂Mn₂GaO₈-ɗ : a new vacancy-ordered perovskite structurecitations
- 2003Synthesis and Characterisation of the Reduced Double-Layer Manganite Sr₃Mn₂O₆₊xcitations
- 2002Structures & Magnetic Ordering in the BrownMillerite Phases, Sr₂MnGaO₅ and Ca₂MnALO₅citations
- 2002Synthesis and characterisation of reduced single layer manganite Sr₂MnO₃.₅₊xcitations
- 2001Synthesis and structure of Sr₂MnGaO₅, a new layered manganese oxidecitations
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article
Structure and magnetic properties of the cubic oxide fluoride BaFeO2F
Abstract
Fluorination of the parent oxide, BaFeO3- δ, with polyvinylidine fluoride gives rise to a cubic compound with a = 4.0603(4) Å at 298K. 57Fe Mössbauer spectra confirmed that all the iron is present as Fe3+. Neutron diffraction data showed complete occupancy of the anion sites indicating a composition BaFeO2F, with a large displacement of the iron off-site. The magnetic ordering temperature was determined as TN = 645±5K. Neutron diffraction data at 4.2K established G-type antiferromagnetism with a magnetic moment per Fe3+ ion of 3.95μB. However, magnetisation measurements indicated the presence of a weak ferromagnetic moment which is assigned to the canting of the antiferromagnetic structure. 57Fe Mössbauer spectra in the temperature range 10 to 300K were fitted with a model of fluoride ion distribution that retains charge neutrality of the perovskite unit cell