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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Berry, Frank
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2020Synthesis and characterisation of Sr4Fe3-xCrxO10-δ citations
- 2017Topotactic fluorine insertion into the channels of FeSb2O4-related materials.citations
- 2012Low temperature fluorination of Sr3Fe2O7-x with polyvinylidine fluoride: An X-ray powder diffraction and Mossbauer spectroscopy studycitations
- 2011The synthesis, structure, magnetic and electrical properties of FeSb2-xPbxO4citations
- 2011Structure and magnetic properties of the cubic oxide fluoride BaFeO2Fcitations
- 2010The ionic conductivity and local environment of cations in Bi9ReO17citations
- 2010LaSrCoFeO5, LaSrCoFeO5F and LaSrCoFeO5.5: new La-Sr-Co-Fe perovskitescitations
- 2009Synthesis and characterization of La0.8Sr1.2Co0.5M0.5O4−δ (M=Fe, Mn)citations
- 2001Investigation of defect structures formed by doping tetravalent ions into spinel-related iron oxides using atomistic simulation calculationscitations
- 2001Cation distribution and magnetic structure of the ferrimagnetic spinel NiCO₂O₄citations
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article
Synthesis and characterization of La0.8Sr1.2Co0.5M0.5O4−δ (M=Fe, Mn)
Abstract
The M4+-containing K2NiF4-type phases La0.8Sr1.2Co0.5Fe0.5O4 and La0.8Sr1.2Co0.5Mn0.5O4 have been synthesized by a sol-gel procedure and characterized by X-ray powder diffraction, thermal analysis, neutron powder diffraction and Mossbauer spectroscopy. Oxide ion vacancies are created in these materials via reduction of M4+ to M3+ and of Co3+ to Co2+. The vacancies are confined to the equatorial planes of the K2NiF4-type structure. A partial reduction of Mn3+ to Mn2+ also occurs to achieve the oxygen stoichiometry in La0.8Sr1.2Co0.5Mn0.5O3.6. La0.9Sr1.2Co0.5Fe0.5O3.65 contains Co2+ and Fe3+ ions which interact antiferromagnetically and result in noncollinear magnetic order consistent with the tetragonal symmetry. Competing ferromagnetic and antiferromagnetic interactions in La0.8Sr1.2Co0.5Fe0.5O4, La0.8Sr1.2Co0.5Mn0.5O4 and La0.8Sr1.2Co0.5Mn0.5O3.6 induce spin glass properties in these phases. (C) 2009 Elsevier Inc. All rights reserved.