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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zanchi, E.
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Topics
Publications (10/10 displayed)
- 2021Recent advances on spinel-based protective coatings for solid oxide cell metallic interconnects produced by electrophoretic depositioncitations
- 2021Optimization of electrophoretic deposition technique to control doping and densification of protective spinel coatings for SOC interconnects
- 2021Mn-Co spinel coatings on Crofer 22 APU by electrophoretic deposition: Up scaling, performance in SOFC stack at 850 °C and compositional modificationscitations
- 2020Iron doped manganese cobaltite spinel coatings produced by electrophoretic co-deposition on interconnects for solid oxide cells: Microstructural and electrical characterizationcitations
- 2020Iron doped manganese cobaltite spinel coatings produced by electrophoretic co-deposition on interconnects for solid oxide cells: Microstructural and electrical characterizationcitations
- 2020Iron doped manganese cobaltite spinel coatings produced by electrophoretic co-deposition on interconnects for solid oxide cells: Microstructural and electrical characterizationcitations
- 2019Crosslinked composite polymer electrolytes with Super Li-ion conductive ceramic materials as electrolytes for Lithium batteries
- 2019In-situ Cu-doped MnCo-spinel coatings for solid oxide cell interconnects processed by electrophoretic depositioncitations
- 2019Electrophoretic co-deposition of Fe2O3 and Mn1,5Co1,5O4: Processing and oxidation performance of Fe-doped Mn-Co coatings for solid oxide cell interconnectscitations
- 2019Electrophoretic co-deposition of Fe 2 O 3 and Mn 1,5 Co 1,5 O 4 : processing and oxidation performance of Fe-doped Mn-Co coatings for solid oxide cell interconnectscitations
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article
Iron doped manganese cobaltite spinel coatings produced by electrophoretic co-deposition on interconnects for solid oxide cells: Microstructural and electrical characterization
Abstract
We report a systematic microstructural and electrical characterization of iron doped Mn–Co spinel coatings processed by electrophoretic co-deposition of Mn<sub>1.5</sub>Co<sub>1.5</sub>O<sub>4 </sub>and Fe<sub>2</sub>O<sub>3</sub> powders on Crofer 22 APU and AISI 441 steel substrates. Iron addition to Mn–Co spinel coating leads to a reduction of the area specific resistance on both substrates, after 3200 h at 750 °C. The Fe doped Mn–Co coating both leads to a thinner oxide scale and reduces the sub scale oxidation for the Crofer 22 APU substrate. Fe doped Mn–Co on AISI 441 shows both a thicker oxide scale and low area specific resistance values, likely due to a doping effect of the oxide scale by minor alloying elements. The different mechanisms by which iron doping of Mn–Co spinels can influence elemental interdiffusion at the steel-oxide scale-coating interfaces and relative contributions to the overall area specific resistance are evaluated by means of advanced electron microscopy. The promising results are further confirmed in a cell test, where the Fe doped MnCo coated interconnect does not induce any degradation of the oxygen electrode, proving its efficiency.