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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kær, Søren Knudsen
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Topics
Publications (12/12 displayed)
- 2019Hydrogen mass transport resistance changes in a high temperature polymer membrane fuel cell as a function of current density and acid dopingcitations
- 2019Hydrogen mass transport resistance changes in a high temperature polymer membrane fuel cell as a function of current density and acid dopingcitations
- 2019The influence of ferric ion impurities on a proton exchange membrane electrolyzer operated at varying temperature and current density conditions
- 2019Influence of the operation mode on PEM water electrolysis degradationcitations
- 2019Influence of the operation mode on PEM water electrolysis degradationcitations
- 2019Long-term contamination effect of iron ions on cell performance degradation of proton exchange membrane water electrolysercitations
- 2018The Influence of Phosphoric Acid Migration on the Performance of High Temperature Polymer Electrolyte Fuel Cellscitations
- 2017Analysing Gas-Liquid Flow in PEM Electrolyser Micro-Channels Using a Micro-Porous Ceramic as Gas Permeable Wallcitations
- 2017Analysing Gas-Liquid Flow in PEM Electrolyser Micro-Channels Using a Micro-Porous Ceramic as Gas Permeable Wallcitations
- 2011Modelling multiphase flow inside the porous media of a polymer electrolyte membrane fuel cell
- 2010Thin film thermocouples for in situ membrane electrode assembly temperature measurements in a polybenzimidazole-based high temperature proton exchange membrane unit cellcitations
- 2010Thin film thermocouples for in situ membrane electrode assembly temperature measurements in a polybenzimidazole-based high temperature proton exchange membrane unit cellcitations
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article
Long-term contamination effect of iron ions on cell performance degradation of proton exchange membrane water electrolyser
Abstract
It is known that impurities, especially metal ions in feed water, can cause significant performance degradation of proton exchange membrane water electrolyser (PEM WE). In this study, the long-term effect of iron ion contamination on single cell performance is investigated by introducing Fe2 (SO4)3 into deionized water fed in PEM WE. Electrochemical impedance spectroscopy (EIS) and polarization curve results were recorded during the test. Results show that with 1 parts per million (ppm, molar ratio) Fe3+ contamination at the test condition of 0.5 A/cm2 and 60 °C, the cell performance degrades severely, especially the charge and mass transfer resistances increase significantly with time. Resistance values obtained through fitting the experiment data with equivalent circuit model were used to better describe the results. The results of Scanning Electron Microscope (SEM) and Energy Dispersive X-ray Spectroscopy (EDX) test illustrate that the existence of Fe3+ promote the Fenton reaction, leading to the production of chemical radicals, which degrade the membrane and anode catalyst layer severely.