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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Thompson, Stephen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Electron Beam and Thermal Stabilities of MFM-300(M) Metal-Organic Frameworkscitations
- 2019Sub-lattice polarization states in anti-ferroelectrics and their relaxation processcitations
- 2017New synchrotron powder diffraction facility for long-duration experimentscitations
- 2015Advances in synchrotron x-ray diffraction and transmission electron microscopy techniques for the investigation of microstructure evolution in proton- and neutron-irradiated zirconium alloyscitations
- 2014The fabrication of a bifunctional oxygen electrode without carbon components for alkaline secondary batteriescitations
- 2011High-resolution synchrotron X-ray diffraction studies of size and strain effects in a complex Al–Fe–Cr–Ti alloy
- 2007A novel approach to dynamic modelling of polymer extrusion for improved process controlcitations
- 2007A Soft Sensor for viscosity control of polymer extrusioncitations
- 2004The structure and thermal expansion behaviour of ikaite, CaCO3. 6H2O, from T = 114 to T = 293 Kcitations
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article
The fabrication of a bifunctional oxygen electrode without carbon components for alkaline secondary batteries
Abstract
The fabrication of a gas diffusion electrode (GDE) without carbon components is described. It is therefore suitable for use as a bifunctional oxygen electrode in alkaline secondary batteries. The electrode is fabricated in two stages (a) the formation of a PTFE-bonded nickel powder layer on a nickel foam substrate and (b) the deposition of a NiCo<sub>2</sub>O<sub>4</sub> spinel electrocatalyst layer by dip coating in a nitrate solution and thermal decomposition. The influence of modifications to the procedure on the performance of the GDEs in 8 M NaOH at 333 K is described. The GDEs can support current densities up to 100 mA cm<sup>-2</sup> with state-of-the-art overpotentials for both oxygen evolution and oxygen reduction. Stable performance during >50 successive, 1 h oxygen reduction/evolution cycles at a current density of 50 mA cm<sup>-2</sup> has been achieved.