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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Grenèche, Jean-Marc
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Influence of Nd Substitution on the Phase Constitution in (Zr,Ce)Fe10Si2 Alloys with the ThMn12 Structurecitations
- 2018Exchange-Biased Fe 3− x O 4 -CoO Granular Composites of Different Morphologies Prepared by Seed-Mediated Growth in Polyol: From Core-Shell to Multicore Embedded Structurescitations
- 2017Atomic scale modeling of iron-doped biphasic calcium phosphate bioceramicscitations
- 2016Structural behavior of laser-irradiated γ-Fe 2 O 3 nanocrystals dispersed in porous silica matrix : γ-Fe 2 O 3 to α-Fe 2 O 3 phase transition and formation of ε-Fe 2 O 3citations
- 2016New iron tetrazolate frameworks : synthesis temperature effect, thermal behaviour, Mössbauer and magnetic studiescitations
- 2015Structural investigations of iron oxynitride multilayered films obtained by reactive gas pulsing processcitations
- 2015New iron tetrazolate frameworkscitations
- 2015New iron tetrazolate frameworks:synthesis temperature effect, thermal behaviour, Mössbauer and magnetic studiescitations
- 2014Magnetic Iron Oxide Nanoparticles: Reproducible Tuning of the Size and Nanosized-Dependent Composition, Defects, and Spin Cantingcitations
- 2014Exchange-biased oxide-based core-shell nanoparticles produced by seed-mediated growth in polyolcitations
- 2013Isomorphous Substitution in a Flexible Metal–Organic Framework: Mixed-Metal, Mixed-Valent MIL-53 Type Materialscitations
- 2012Insights into the Mechanism Related to the Phase Transition from γ-Fe2O3 to α-Fe2O3 Nanoparticles Induced by Thermal Treatment and Laser Irradiationcitations
- 2012Development of new anodes compatible with the solid oxide fuel cell electrolyte BaIn0.3Ti0.7O2.85citations
- 2004The titration of clay minerals I. Discontinuous backtitration technique combined with CEC measurements.citations
- 2000Microstructural and magnetic properties of Fe/Cr-substituted ferrite compositescitations
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article
Development of new anodes compatible with the solid oxide fuel cell electrolyte BaIn0.3Ti0.7O2.85
Abstract
new family of MIEC compounds resulting from the electrolyte BaIn0.3Ti0.7O2.85 (BIT07) was developed by coupled substitution of titanium by iron and barium by lanthanum. Total conductivity increases significantly with iron and lanthanum content. BaIn0.3Ti0.7O2.85 yields a total conductivity in air of 10−2 S cm−1 at 700 °C whereas that of Ba0.7La0.3In0.3Ti0.1Fe0.6O3−δ (BLITFe06) is 3 S cm−1. Doped compounds are p-type conductors. In reducing atmosphere the electrical conductivity decreases drastically to σ = 2 × 10−2 S cm−1 for the best value, which is not sufficient for a use as MIEC anode. Nevertheless, Ni/BLITFe06 cermets seem to be good candidates as SOFC anodes. The total conductivity of Ni/BLITFe cermets is higher than that of 18.7 vol.% Ni/BIT07 (σ700 °C ≈ 102 S cm−1), even for a lower Ni content (16.1 vol.% Ni/BLITFe σ700 °C ≈ 200 S cm−1). The percolation threshold moves towards the small quantities of nickel (from 15.7 vol.% to 10 vol.%). Ni/BLITFe06 cermets, compared with Ni/BIT07, show a better electrochemical behaviour towards fuel oxidation.