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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bonanos, Nikolaos
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (35/35 displayed)
- 2016The A-cation Deficient Perovskite Series La2-xCoTiO6-δ (0≤x≤0.20): new Potential Cathodes for Solid Oxide Fuel Cells.
- 2016Conductivity and structure of sub-micrometric SrTiO 3 -YSZ compositescitations
- 2016The A-cation deficient perovskite series La 2-x CoTiO 6-δ (0 ≤ x ≤ 0.20): new components for potential SOFC composite cathodescitations
- 2016Conductivity and structure of sub-micrometric SrTiO3-YSZ compositescitations
- 2015On the Defect Chemistry, Electrical Properties and Electrochemical Performances As Solid Oxide Fuel Cell Cathode Materials of New La-(Sr/Vac)-Co-Ti-O Perovskites
- 2014Optimization of Ferritic Steel Porous Supports for Protonic Fuel Cells Working at 600°C
- 2014Optimization of Ferritic Steel Porous Supports for Protonic Fuel Cells Working at 600°C
- 2014High performance and highly durable infiltrated cathodes using Pr-modified Ce0.9Gd0.1O1.95 backbone
- 2014High performance and highly durable infiltrated cathodes using Pr-modified Ce 0.9 Gd 0.1 O 1.95 backbone
- 2013Synthesis by spark plasma sintering of a novel protonic/electronic conductor composite: BaCe0.2Zr0.7Y0.1O3-delta /Sr0.95Ti0.9Nb0.1O3-delta (BCZY27/STN95)citations
- 2013Synthesis by spark plasma sintering of a novel protonic/electronic conductor composite: BaCe 0.2 Zr 0.7 Y 0.1 O 3−δ /Sr 0.95 Ti 0.9 Nb 0.1 O 3−δ (BCZY27/STN95)citations
- 2013High performance fuel electrode for a solid oxide electrochemical cell
- 2013Impedance Spectroscopy of Dielectrics and Electronic Conductorscitations
- 2013Sintering process optimization for multi-layer CGO membranes by in situ techniquescitations
- 2013Effective improvement of interface modified strontium titanate based solid oxide fuel cell anodes by infiltration with nano-sized palladium and gadolinium-doped cerium oxidecitations
- 2013A modified anode/electrolyte structure for a solid oxide electrochemical cell and a method for making said structure
- 2012Conductivity study of dense BaCex Zr(0.9-x)Y0.1O(3 − δ) prepared by solid state reactive sintering at 1500 deg. Ccitations
- 2012A Preliminary Study on WO3‐Infiltrated W–Cu–ScYSZ Anodes for Low Temperature Solid Oxide Fuel Cellscitations
- 2012A Preliminary Study on WO 3 ‐Infiltrated W–Cu–ScYSZ Anodes for Low Temperature Solid Oxide Fuel Cellscitations
- 2012Characterization of La0.995Ca0.005NbO4/Ni anode functional layer by electrophoretic deposition in a La0.995Ca0.005NbO4 electrolyte based PCFCcitations
- 2012Fabrication of supported Ca-doped lanthanum niobate electrolyte layer and NiO containing anode functional layer by electrophoretic depositioncitations
- 2012Efficient ceramic anodes infiltrated with binary and ternary electrocatalysts for SOFCs operating at low temperaturescitations
- 2012Electrical Conductivity of 10 mol% Sc2O3-1 mol% M2O3-ZrO2 Ceramicscitations
- 2012Highly durable anode supported solid oxide fuel cell with an infiltrated cathodecitations
- 2012Electrochemical characterization of infiltrated Bi2V0.9Cu0.1O5.35 cathodes for use in low temperature solid oxide fuel cellscitations
- 2011Enhanced electrochemical performance of the solid oxide fuel cell cathode using Ca3Co4O9+δcitations
- 2010Sintering effect on material properties of electrochemical reactors used for removal of nitrogen oxides and soot particles emitted from diesel enginescitations
- 2010Sintering effect on material properties of electrochemical reactors used for removal of nitrogen oxides and soot particles emitted from diesel enginescitations
- 2010The Effect of a CGO Barrier Layer on the Performance of LSM/YSZ SOFC Cathodescitations
- 2009Ionic conductivity and thermal stability of magnetron-sputtered nanocrystalline yttria-stabilized zirconiacitations
- 2008Electrical conductivity and oxygen exchange kinetics of La2NiO4+delta thin films grown by chemical vapor depositioncitations
- 2008Electrical conductivity and oxygen exchange kinetics of La2NiO4+ thin films grown by chemical vapor depositioncitations
- 2004Factors controlling the oxide ion conductivity of fluorite and perovskite structured oxidescitations
- 2004The role of dopant concentration, A-site deficiency and processing on the electrical properties of strontium- and titanium-doped lanthanum scandatecitations
- 2000Effect of electrode material on the oxidation of H2 at the metal-Sr0.995Ce0.95Y0.05O2.970 interfacecitations
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article
Enhanced electrochemical performance of the solid oxide fuel cell cathode using Ca3Co4O9+δ
Abstract
This paper reports on the electrochemical performance of an SOFC cathode for potential use in intermediate-temperature solid oxide fuel cells (IT-SOFCs) using the oxygen non-stoichiometric misfit-layered cobaltite Ca3Co4O9+δ or composites of Ca3Co4O9+δ with Ce0.9Gd0.1O1.95 (CGO/Ca3Co4O9+δ). Electrochemical impedance spectroscopy revealed that symmetric cells with an electrode of pure Ca3Co4O9+δ exhibit a cathode polarization resistance (Rp) of 12.4 Ω cm2, at 600 °C in air. Strikingly, Rp of the composite CGO/Ca3Co4O9+δ with 50 vol.% CGO was reduced by a factor of 19 (i.e. Rp = 0.64 Ω cm2), the lowest value reported so far for the Ca3Co4O9 family of compounds. These findings together with the reported thermal expansion coefficient, good compatibility with CGO and chemical durability of this material suggest that it is a promising candidate cathode for IT-SOFCs.