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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Armand, Michel
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Transport Properties and Local Ions Dynamics in LATP‐Based Hybrid Solid Electrolytescitations
- 2022Interface Stability between Na3Zr2Si2PO12 Solid Electrolyte and Sodium Metal Anode for Quasi-Solid-State Sodium Batterycitations
- 2021Considering lithium-ion battery 3D-printing via thermoplastic material extrusion and polymer powder bed fusioncitations
- 2020Overview on Lithium-Ion Battery 3D-Printing By Means of Material Extrusioncitations
- 2020Poly(Ethylene Oxide)-LiTFSI Solid Polymer Electrolyte Filaments for Fused Deposition Modeling Three-Dimensional Printingcitations
- 2019Three-Dimensional Printing of a LiFePO4/Graphite Battery Cell via Fused Deposition Modelingcitations
- 2019Fluorine‐Free Noble Salt Anion for High‐Performance All‐Solid‐State Lithium–Sulfur Batteriescitations
- 2019Single-ion conducting poly(ethylene oxide carbonate) as solid polymer electrolyte for lithium batteriescitations
- 2018The effect of cation chemistry on physicochemical behaviour of superconcentrated NaFSI based ionic liquid electrolytes and the implications for Na battery performancecitations
- 2016Novel Na+ ion diffusion mechanism in mixed organic-inorganic ionic liquid electrolyte leading to high Na+ transference number and stable, high rate electrochemical cycling of sodium cellscitations
- 2016Stable zinc cycling in novel alkoxy-ammonium based ionic liquid electrolytescitations
- 2010Detailed studies on the fillers modification and their influence on composite, poly(oxyethylene)-based polymeric electrolytescitations
- 2009Ceramic-in-polymer versus polymer-in-ceramic polymeric electrolytes—A novel approachcitations
- 2009Modern generation of polymer electrolytes based on lithium conductive imidazole saltscitations
- 2007FLUOROSULPHONATED ELASTOMERS WITH LOW GLASS TRANSITION BASED OF VINYLIDENE FLUORIDE
Places of action
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article
Modern generation of polymer electrolytes based on lithium conductive imidazole salts
Abstract
In this paper the application of completely new generation imidazole-derived salts in a model polymer electrolyte is described. As a polymer matrix, two types of liquid low molecular weight PEO analogues e.g. dimethyl ether of poly(ethylene glycol) of 500 g mol−1 average molar mass (PEGDME500) and methyl ether of poly(ethylene glycol) of 350 g mol−1 average molar mass (PEGME350) were used. Room temperature conductivities measured by electrochemical impedance spectroscopy were found to be as high as 10−3–10−4 S cm−1 in the 0.1–1 mol dm−3 range of salt concentrations. Li+ transference numbers higher than 0.5 were measured and calculated using the Bruce–Vincent method. For a complete electrochemical characterization the interphase resistance stability over time was carefully monitored for a period of 30 days. Structural analysis and interactions between electrolyte components were done by Raman spectroscopy. Fuoss–Kraus semiempirical method was applied for estimation of free ions and ionic agglomerates showing that fraction of ionic agglomerates for salt concentration of 0.1–1 mol dm−3 is much lower than in electrolytes containing LiClO4 in corresponding concentrations.