693.932 PEOPLE
| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Maurice, Vincent
Institut de Recherche de Chimie Paris
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (56/56 displayed)
- 2024Studies on He and Ne gas permeation in microfabricated cells using Al2O3 coatings
- 2024On the reduction of gas permeation through the glass windows of micromachined vapor cells using Al2O3 coatings
- 2024Molybdenum effects on the stability of passive films unraveled at the nanometer and atomic scalescitations
- 2024Hydroxyl transport mechanisms upon passivation of Cr-Fe-Co-Ni-Mo multi-principal element alloy surfaces investigated by isotopic labellingcitations
- 2023Effects of Chloride Ions on Passive Oxide Films Formed on Cr-Fe-Co-Ni(-Mo) Multi-Principal Element Alloy Surfacescitations
- 2023Corrosion inhibition at emergent grain boundaries studied by DFT for 2-mercaptobenzothiazole on bi-crystalline coppercitations
- 2023XPS study of the thermal stability of passivated NiCrFeCoMo multi‐principal element alloy surfacescitations
- 2023XPS study of the thermal stability of passivated NiCrFeCoMo multi‐principal element alloy surfacescitations
- 2023Adsorption of 2-Mercaptobenzothiazole Organic Inhibitor and its Effects on Copper Anodic Oxidation in Alkaline Environmentcitations
- 2023Early-stage surface oxidation of the equiatomic CoCrFeMnNi high entropy alloy studied in situ by XPScitations
- 2023Load cell based on binocular test body and SAW strain sensor with a Radio-Frequency Reflectometry Read-Out System.
- 2023Origin of enhanced passivity of Cr–Fe–Co–Ni–Mo multi-principal element alloy surfacescitations
- 2023Effect of surface preparation by high-temperature hydrogen annealing on the passivation of Ni-20 at.% Cr alloy in sulfuric acidcitations
- 2023Effect of surface preparation by high-temperature hydrogen annealing on the passivation of Ni-20 at.% Cr alloy in sulfuric acidcitations
- 2023Reduction of helium permeation in microfabricated cells using aluminosilicate glass substrates and Al2O3 coatingscitations
- 2022Enhanced passivity of Cr-Fe-Co-Ni-Mo multi-component single-phase face-centred cubic alloys: design, production and corrosion behaviourcitations
- 2022XPS study of oxide nucleation and growth mechanisms on a model FeCrNiMo stainless steel surfacecitations
- 2022Can We Enhance Passivity with a Surface Finish? Spectroscopic and Electrochemical Analysis on 316L Stainless Steelcitations
- 2022Can we enhance passivity with a surface finish?citations
- 2021An XPS and ToF-SIMS study of the passive film formed on a model FeCrNiMo stainless steel surface in aqueous media after thermal pre-oxidation at ultra-low oxygen pressurecitations
- 2021An XPS and ToF-SIMS study of the passive film formed on a model FeCrNiMo stainless steel surface in aqueous media after thermal pre-oxidation at ultra-low oxygen pressurecitations
- 2021In situ scanning tunneling microscopy study of 2-mercaptobenzimidazole local inhibition effects on copper corrosion at grain boundary surface terminationscitations
- 2021Atomic Scale Insight into Corrosion Inhibition: DFT Study of 2-Mercaptobenzimidazole on Locally De-Passivated Copper Surfacescitations
- 2021Corrosion inhibition of locally de-passivated surfaces by DFT study of 2-mercaptobenzothiazole on coppercitations
- 2021Local Effects of Organic Inhibitor Molecules on Passivation of Grain Boundaries Studied In Situ on Coppercitations
- 2021Nanoscale early oxidation mechanisms of model FeCrNi austenitic stainless steel surfaces at room temperaturecitations
- 2021Insight on passivity of high entropy alloys: thermal stability and ion transport mechanisms in the passive oxide film on CoCrFeMnNi surfacescitations
- 2020Chloride-induced alterations of the passive film on 316L stainless steel and blocking effect of pre-passivationcitations
- 20202-mercaptobenzothiazole corrosion inhibitor deposited at ultra-low pressure on model copper surfacescitations
- 2020Passivation-Induced Cr and Mo Enrichments of 316L Stainless Steel Surfaces and Effects of Controlled Pre-Oxidation
- 2020Passivation mechanisms and pre-oxidation effects on model surfaces of FeCrNi austenitic stainless steelcitations
- 2020Local Inhibition by 2-mercaptobenzothiazole of Early Stage Intergranular Corrosion of Copper
- 2019Mechanisms of Cr and Mo Enrichments in the Passive Oxide Film on 316L Austenitic Stainless Steelcitations
- 2019Origin of nanoscale heterogeneity in the surface oxide film protecting stainless steel against corrosioncitations
- 2018Nanoscale Intergranular Corrosion and Relation with Grain Boundary Character as Studied In Situ on Coppercitations
- 2018Progress in corrosion science at atomic and nanometric scalescitations
- 2018New insight on early oxidation stages of austenitic stainless steel from in situ XPS analysis on single-crystalline Fe–18Cr–13Nicitations
- 2018The effect of Na2S additive in alkaline electrolyte on improved performances of Fe-based air batteriescitations
- 2017Use of local electrochemical methods (SECM, EC-STM) and AFM to differentiate microstructural effects (EBSD) on very pure coppercitations
- 2017Use of local electrochemical methods (SECM, EC-STM) and AFM to differentiate microstructural effects (EBSD) on very pure coppercitations
- 2017Effect of high temperature oxidation process on corrosion resistance of bright annealed ferritic stainless steelcitations
- 2016The role of surface preparation in corrosion protection of copper with nanometer-thick ALD alumina coatingscitations
- 2014Interface control of atomic layer deposited oxide coatings by filtered cathodic arc deposited sublayers for improved corrosion protectioncitations
- 2014Sealing of Hard CrN and DLC Coatings with Atomic Layer Depositioncitations
- 2013Tantalum oxide nanocoatings prepared by atomic layer and filtered cathodic arc deposition for corrosion protection of steelcitations
- 2013AlxTayOz Mixture Coatings Prepared Using Atomic Layer Deposition for Corrosion Protection of Steelcitations
- 2013Hydrogen-argon plasma pre-treatment for improving the anti-corrosion properties of thin Al2O3 films deposited using atomic layer deposition on steelcitations
- 2011Failure mechanism of thin Al2O3 coatings grown by atomic layer deposition for corrosion protection of carbon steelcitations
- 2011Corrosion Protection of Steel with Oxide Nanolaminates Grown by Atomic Layer Depositioncitations
- 2011Electrochemical and time-of-flight secondary ion mass spectrometry analysis of ultra-thin metal oxide (Al2O3 and Ta2O5) coatings deposited by atomic layer deposition on stainless steelcitations
- 2011Electrochemical and time-of-flight secondary ion mass spectrometry analysis of ultra-thin metal oxide (Al2O3 and Ta2O5) coatings deposited by atomic layer deposition on stainless steelcitations
- 2011Low-temperature atomic layer deposition of Al2O3 thin coatings for corrosion protection of steelcitations
- 2009Atomistic modeling of voiding mechanisms at oxide/alloy interfacescitations
- 2008Li-ion intercalation in thermal oxide thin films of MoO3 as studied by XPS, RBS, and NRAcitations
- 2007Ageing of V2O5 thin films induced by Li intercalation multi-cyclingcitations
- 2005Effect of platinum on the growth rate of the oxide scale formed on cast nickel aluminide intermetallic alloyscitations
Places of action
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article
Ageing of V2O5 thin films induced by Li intercalation multi-cycling
Abstract
International audience ; Cyclic voltammetry, XPS, RBS and AFM have been combined to study the ageing mechanism of Li intercalation in V2O5 thin films prepared by thermal oxidation of vanadium metal. Multi-cycling tests were performed in 1 M LiClO4-PC in the potential range E epsilon [3.8, 2.8 V] versus Li/Li+, corresponding to the alpha-to-delta phase transition. XPS and AFM were performed using direct anaerobic and anhydrous transfer. Capacity fading remains inferior to 20% during similar to 2500 cycles. XPS shows slight modifications of the oxide composition with a V4+ concentration increasing from similar to 5% prior to cycling to similar to 16-27% after cycling, due to Li trapped in the oxide film and to the loss of V2O5 active material. The presence of lithium carbonate and lithium-alkyl carbonate species evidences the formation of the so-called SEI layer. AFM evidences the loss of crystalline material by grain exfoliation from the outer V2O5 layer of the oxide film. By further exfoliation, the inner VO2 layer of the oxide film is reached and pits are formed, occupying similar to 9-13% of the surface. This de-cohesion at grain boundaries is attributed to the strain generated by repeated lattice distortions. After 3300 cycles, the disappearance of lithium carbonates, whereas Li-alkyl carbonates and/or Li-alkoxides remain on the surface, indicates the dissolution and/or conversion of the SEI layer. After 4500 cycles, the oxide film became very labile and could be stripped away by rinsing to reveal the vanadium metal substrate. (C) 2007 Elsevier B.V. All rights reserved.