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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Nyokong, Tebello
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023High-performance non-enzymatic glucose sensing on nanocomposite electrocatalysts of nickel phthalocyanine nanorods and nitrogen doped-reduced graphene oxide nanosheetscitations
- 2022Photodynamic activity of novel cationic porphyrins conjugated to graphene quantum dots against <i>Staphylococcus aureus</i>citations
- 2021Low temperature scalable synthetic approach enabling high bifunctional electrocatalytic performance of NiCo 2 S 4 and CuCo 2 S 4 thiospinelscitations
- 2020Electrodeposited Benzothiazole Phthalocyanines for Corrosion Inhibition of Aluminium in Acidic Mediumcitations
- 2018In-situ synthesis of gold nanoparticles on graphene quantum dots-phthalocyanine nanoplatformscitations
- 2017Nonlinear Interactions of Zinc Phthalocyanine-Graphene Quantum Dots Nanocompositescitations
- 2016Application of graphene quantum dots decorated with TEMPO-derivatized zinc phthalocyanine as novel nanoprobescitations
- 2016Fluorescence properties of alloyed ZnSeS quantum dots overcoated with ZnTe and ZnTe/ZnS shellscitations
- 2015Optical properties of water-soluble l-cysteine-capped alloyed CdSeS quantum dot passivated with ZnSeTe and ZnSeTe/ZnS shellscitations
- 2013Photodynamic inactivation of Staphylococcus aureus using low symmetrically substituted phthalocyanines supported on a polystyrene polymer fibercitations
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article
In-situ synthesis of gold nanoparticles on graphene quantum dots-phthalocyanine nanoplatforms
Abstract
<p>Owing to the need for new low-dimensional molecular assemblies with tailored electronic properties, the current study presents a facile approach for the synthesis and assembly of gold nanoparticles (AuNPs) onto functional graphene quantum dots (GQDs)-phthalocyanines (Pcs) arrays and the investigation of their photophysical and surface enhanced Raman scattering (SERS) properties. The GQDs were functionalized with L-glutathione (GSH) (to form GQDs@GSH) in order to assist coupling to the low symmetry Zn tris–(tert–butyl) mono carboxyphenoxy (propionic acid) phthalocyanine (complex 1) to form 1@GQDs. The affinity of gold (Au) to sulphur (S) was exploited for the assembly of the AuNPs onto 1@GQDs platform to form 1@GQDs-AuNPs. Transmission electron microscopic investigations confirmed the formation of monodispersed, spherical Pc/GQDs@GSH/AuNPs hybrids. The nanocomposite displayed high triplet quantum yields, which translated into high singlet oxygen quantum yield as high as 87%. Furthermore, the formed composites demonstrated strong surface enhanced Raman scattering (SERS) properties with an unprecedented intrinsic maximal enhancement factor of more than 30-fold. These nanostructures also retain more than 90% of their original SERS intensities after a week of storage, displaying superb stability under ambient conditions. These results highlight the remarkable potential of this composite as a unique Raman-based PDT dosimetric agent.</p>