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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Tillard, Monique
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2021Growth, single-crystal structure, and magnetic properties of the double molybdate KYb(MoO4)2citations
- 2021Structural and Vibrational Study of CsSbGe3O9, a New Germanate in the ASbGe3O9 Family (A = Alkali Metal)citations
- 2021Two novel macrocyclic organotin (IV) carboxylates based on bipyrazoledicarboxylic acid derivatives: Syntheses, crystal structures and antifungal activitiescitations
- 2021The open-framework structure of KSbGe3O9 flux-grown crystals investigated by X-ray diffraction, vibrational spectroscopy, and DFT calculationscitations
- 2021Flux growth synthesis, single crystal and electronic structure of the new intermetallic compound Pt2Ga17Ta3
- 2021Structure, vibrational and magnetic characteristics of LiYbX2O8 (X = W, Mo) single-crystalscitations
- 2020Single-crystal growth, structure, and optical properties of a new non-centrosymmetric germanate, RbSbGe3O9citations
- 2020Exploration in the Sc-Al-Cu system: evidence for i -ScAl~2.4~Cu~3.2~ quasicrystal and new crystal data for five intermetallic phasescitations
- 2016On the adaptability of 1/1 cubic approximant structure in the MgAlZn system with the particular example of Mg32Al12Zn2Zn37citations
- 2016A phase width for CaGaSn. Crystal structure of mixed intermetallic Ca4Ga4+xSn4−x and SmGaxSn3−x, stability, geometry and electronic structure
- 2015Mg2Al3, a complex and disordered intermetallic compound as anode material for metal-air batteriescitations
- 2014The mixed intermetallic silicide Nb5-xTaxSi3 (0 ≤ x ≤ 5). Crystal and electronic structure.citations
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article
Growth, single-crystal structure, and magnetic properties of the double molybdate KYb(MoO4)2
Abstract
Crystals of the rare earth double molybdate KYb(MoO4)2 were grown by spontaneous nucleation from a K2Mo4O13 flux. The typical crystals were colorless and elongated, well-developed plates. The material has been characterized by powder X-ray diffraction (PXRD), energy-dispersive X-ray spectrometry (EDS), and Raman spectroscopy methods. The structural properties have been investigated through single-crystal X-ray diffraction at room temperature. KYb(MoO4)2 crystallizes in the orthorhombic symmetry, space group Pbcn (No. 60), a = 5.0395(2), b = 18.2821(9), c = 7.8635(4) Å, and Z = 4. A complete ordering of the Yb3+ and Mo6+ cations has been found. The Yb3+ ions are located in distorted YbO8 antiprisms which form chains of edge-sharing, aligned along the c-axis while the Mo6+ ions are placed in a slightly deformed tetrahedral environment of oxygen atoms. Double bridge modes of the “Mo2O8 dimers” have been identified in the unpolarized Raman spectra. The temperature-dependent magnetic susceptibility of KYb(MoO4)2 follows a Curie–Weiss law with a Weiss constant of −52 K.