| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Chalmers, Brian Alexander
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2021Synthetic and structural study of peri-substituted phosphine-arsinescitations
- 2018A study of through-space and through-bond JPP coupling in a rigid nonsymmetrical bis(phosphine) and its metal complexescitations
- 2016Rhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligandscitations
- 2016Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interactioncitations
- 2015Rhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligandscitations
- 2015A synthetic, spectroscopic and structural examination of phosphorus, arsenic and antimony peri-substituted acenaphthenes
- 2015Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interactioncitations
- 2015Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interactioncitations
Places of action
| Organizations | Location | People |
|---|
article
Rhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligands
Abstract
The syntheses of rhodium(III) and iridium(III) half sandwich complexes containing tertiary arsine and stibine ligands of the form [Cp*M(L)Cl 2 ] (M = Rh, Ir; L = AsEt 3 , AsPh 3 , SbPh 3 ) are reported. These compounds represent infrequent examples of rhodium and iridium metal complexes bearing arsenic or antimony ligands. All new compounds were fully characterised using 1 H and 13 C NMR spectroscopy, mass spectrometry and single crystal X-ray diffraction. DFT calculations show the formation of the complexes from (Cp*MCl 2 ) 2 and EPh 3 (E = P, As, Sb) to be highly exothermic, although the enthalpic driving force is decreasing in the expected sequence P > As > Sb.